TY - JOUR
T1 - Visible light antibacterial potential of graphene-TiO2 cementitious composites for self-sterilization surface
AU - HAMDANY, ABDUL HALIM
AU - Ding, Yuanzhao
AU - Qian, Shunzhi
PY - 2022
Y1 - 2022
N2 - Graphene oxide-titanium dioxide (GO-TiO2) composite was synthesized with one step hydrothermal process. The structure and morphology were characterized by field-emission-scanning-electron-microscopy, Thermogravimetric analysis, X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Photocatalytic activity against Escherichia coli inactivation was carried out by GO-TiO2 mixed with cement composite under visible light. The result revealed no significant difference between morphology of GO-TiO2 and pristine TiO2. FESEM and FTIR results showed the presence of carbon component in the GO-TiO2 composites. TGA-IR confirmed that the GO content (3%) in the composite could be controlled during the synthesis process. The synthesized GO-TiO2 had stronger visible light absorption and narrower bandgap (3.11 eV) than TiO2 (3.21 eV). The bandgap reduction was also observed in cement sample with GO-TiO2 (3.08 eV) which could be beneficial for reducing the energy needed for photoexcitation. As a result, the specimen with GO-P25 outperformed specimens with others for Escherichia coli inactivation.
AB - Graphene oxide-titanium dioxide (GO-TiO2) composite was synthesized with one step hydrothermal process. The structure and morphology were characterized by field-emission-scanning-electron-microscopy, Thermogravimetric analysis, X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Photocatalytic activity against Escherichia coli inactivation was carried out by GO-TiO2 mixed with cement composite under visible light. The result revealed no significant difference between morphology of GO-TiO2 and pristine TiO2. FESEM and FTIR results showed the presence of carbon component in the GO-TiO2 composites. TGA-IR confirmed that the GO content (3%) in the composite could be controlled during the synthesis process. The synthesized GO-TiO2 had stronger visible light absorption and narrower bandgap (3.11 eV) than TiO2 (3.21 eV). The bandgap reduction was also observed in cement sample with GO-TiO2 (3.08 eV) which could be beneficial for reducing the energy needed for photoexcitation. As a result, the specimen with GO-P25 outperformed specimens with others for Escherichia coli inactivation.
KW - antibacterial; cementitious composites; Escherichia coli inactivation; graphene oxide; titanium dioxide
U2 - 10.1080/21650373.2022.2143451
DO - 10.1080/21650373.2022.2143451
M3 - Article
SN - 2165-0373
JO - Journal of Sustainable Cement-Based Materials
JF - Journal of Sustainable Cement-Based Materials
ER -