TY - JOUR
T1 - Use of carbon pyrolyzed from rice husk in LiFePO4/V/C composite and its performance for lithium ion battery cathode
AU - Sofyan, N.
AU - Sekaringtyas, P.
AU - Zulfia, A.
AU - Subhan, A.
N1 - Funding Information:
The authors would like to express their gratitude and appreciation for the funding from the Directorate of Research and Community Services (DRPM), Universitas Indonesia, through Hibah PITTA No. 822/UN2.R3.1/HKP.05.00/2017.
Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2018/1/25
Y1 - 2018/1/25
N2 - The characteristics of activated carbon pyrolyzed from rice husk used in the synthesis of LiFePO4/V/C for the development of lithium ion battery cathode has been examined. The synthesis was begun by synthesizing LiFePO4 (LFP) via hydrothermal route using the precursors in stoichiometric amounts of LiOH, NH4H2PO4, and FeSO4.7H2O. The assynthesized LFP was then added with variation of vanadium concentrations and a fix concentration of the carbon pyrolyzed from rice husk to form a composite of LiFePO4/V/C. The composites were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and electrochemical impedance spectroscopy (EIS). The XRD results showed that the LiFePO4/V/C has been successfully formed whereas SEM results showed a difference in morphology of vanadium and activated carbon addition. The EIS results showed that the conductivity of LiFePO4/C-0 wt.% V is 1.0196×10-2 S/cm, LiFePO4/C-3 wt.% V is 1.0302×10-2 S/cm, LiFePO4/C-5 wt.% V is 6.1282×10-3 S/cm, and LiFePO4/C-7 wt.% V is 8.3843×10-3 S/cm. The best performance for lithium ion battery cathode was given by LiFePO4/V/C at 3 wt.% vanadium. This result indicated that rice husk can be used as a cheap resource for activated carbon in the development of lithium ion battery cathode.
AB - The characteristics of activated carbon pyrolyzed from rice husk used in the synthesis of LiFePO4/V/C for the development of lithium ion battery cathode has been examined. The synthesis was begun by synthesizing LiFePO4 (LFP) via hydrothermal route using the precursors in stoichiometric amounts of LiOH, NH4H2PO4, and FeSO4.7H2O. The assynthesized LFP was then added with variation of vanadium concentrations and a fix concentration of the carbon pyrolyzed from rice husk to form a composite of LiFePO4/V/C. The composites were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and electrochemical impedance spectroscopy (EIS). The XRD results showed that the LiFePO4/V/C has been successfully formed whereas SEM results showed a difference in morphology of vanadium and activated carbon addition. The EIS results showed that the conductivity of LiFePO4/C-0 wt.% V is 1.0196×10-2 S/cm, LiFePO4/C-3 wt.% V is 1.0302×10-2 S/cm, LiFePO4/C-5 wt.% V is 6.1282×10-3 S/cm, and LiFePO4/C-7 wt.% V is 8.3843×10-3 S/cm. The best performance for lithium ion battery cathode was given by LiFePO4/V/C at 3 wt.% vanadium. This result indicated that rice husk can be used as a cheap resource for activated carbon in the development of lithium ion battery cathode.
UR - http://www.scopus.com/inward/record.url?scp=85041638466&partnerID=8YFLogxK
U2 - 10.1088/1755-1315/105/1/012023
DO - 10.1088/1755-1315/105/1/012023
M3 - Conference article
AN - SCOPUS:85041638466
SN - 1755-1307
VL - 105
JO - IOP Conference Series: Earth and Environmental Science
JF - IOP Conference Series: Earth and Environmental Science
IS - 1
M1 - 012023
T2 - 2nd International Tropical Renewable Energy Conference, i-TREC 2017
Y2 - 3 October 2017 through 4 October 2017
ER -