Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine

Dimas Rahadi Pitoyo; Shinta Sari Hastuningtyas

doi:10.1063/5.0021655

Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine

Sukirno, Dimas Rahadi Pitoyo, Shinta Sari Hastuningtyas

Department of Chemical Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

Gasoline combustion in an engine always produce carbon particle which then agglomerate, precipitate, and degrade the engine performance. In this research PIB amine, a surfactant having PIB as the hydrocarbon nonpolar tail and TEPA as polar head, is prepared and tested as deposit controlling agent (DCA) f or gasoline. This reaction product is a viscous liquid with density 0,8566 g/ml and kinematic viscosity @40°C of 75,16 cSt, and on its FTIR spectrum shows peak at 3200-3500 cm-1 (amine group). Its anti-deposit performance has been tested using single cylinder gasoline engine, at concentration 300 ppm PIB amine can significantly reduce deposit, comparable to that of the commercial PIBA. The 300 ppm PIB Amine gasoline is also pass gum test, with unwash gum value <75mg/100mL and wash gum value <5 mg/100mL.

Original language	English
Title of host publication	4th International Tropical Renewable Energy Conference, i-TREC 2019
Editors	Eny Kusrini, I. Gde Dharma Nugraha
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735420144
DOIs	https://doi.org/10.1063/5.0021655
Publication status	Published - 3 Sept 2020
Event	4th International Tropical Renewable Energy Conference 2019, i-TREC 2019 - Bali, Indonesia Duration: 14 Aug 2019 → 16 Aug 2019

Publication series

Name	AIP Conference Proceedings
Volume	2255
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	4th International Tropical Renewable Energy Conference 2019, i-TREC 2019
Country/Territory	Indonesia
City	Bali
Period	14/08/19 → 16/08/19

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10.1063/5.0021655

Cite this

Sukirno, Pitoyo, D. R., & Hastuningtyas, S. S. (2020). Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine. In E. Kusrini, & I. G. D. Nugraha (Eds.), 4th International Tropical Renewable Energy Conference, i-TREC 2019 Article 0600181 (AIP Conference Proceedings; Vol. 2255). American Institute of Physics Inc.. https://doi.org/10.1063/5.0021655

Sukirno ; Pitoyo, Dimas Rahadi ; Hastuningtyas, Shinta Sari. / Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine. 4th International Tropical Renewable Energy Conference, i-TREC 2019. editor / Eny Kusrini ; I. Gde Dharma Nugraha. American Institute of Physics Inc., 2020. (AIP Conference Proceedings).

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title = "Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine",

abstract = "Gasoline combustion in an engine always produce carbon particle which then agglomerate, precipitate, and degrade the engine performance. In this research PIB amine, a surfactant having PIB as the hydrocarbon nonpolar tail and TEPA as polar head, is prepared and tested as deposit controlling agent (DCA) f or gasoline. This reaction product is a viscous liquid with density 0,8566 g/ml and kinematic viscosity @40°C of 75,16 cSt, and on its FTIR spectrum shows peak at 3200-3500 cm-1 (amine group). Its anti-deposit performance has been tested using single cylinder gasoline engine, at concentration 300 ppm PIB amine can significantly reduce deposit, comparable to that of the commercial PIBA. The 300 ppm PIB Amine gasoline is also pass gum test, with unwash gum value <75mg/100mL and wash gum value <5 mg/100mL. ",

author = "Sukirno and Pitoyo, {Dimas Rahadi} and Hastuningtyas, {Shinta Sari}",

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year = "2020",

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doi = "10.1063/5.0021655",

language = "English",

series = "AIP Conference Proceedings",

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Sukirno, Pitoyo, DR & Hastuningtyas, SS 2020, Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine. in E Kusrini & IGD Nugraha (eds), 4th International Tropical Renewable Energy Conference, i-TREC 2019., 0600181, AIP Conference Proceedings, vol. 2255, American Institute of Physics Inc., 4th International Tropical Renewable Energy Conference 2019, i-TREC 2019, Bali, Indonesia, 14/08/19. https://doi.org/10.1063/5.0021655

Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine. / Sukirno; Pitoyo, Dimas Rahadi; Hastuningtyas, Shinta Sari.
4th International Tropical Renewable Energy Conference, i-TREC 2019. ed. / Eny Kusrini; I. Gde Dharma Nugraha. American Institute of Physics Inc., 2020. 0600181 (AIP Conference Proceedings; Vol. 2255).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine

AU - Sukirno,

AU - Pitoyo, Dimas Rahadi

AU - Hastuningtyas, Shinta Sari

PY - 2020/9/3

Y1 - 2020/9/3

N2 - Gasoline combustion in an engine always produce carbon particle which then agglomerate, precipitate, and degrade the engine performance. In this research PIB amine, a surfactant having PIB as the hydrocarbon nonpolar tail and TEPA as polar head, is prepared and tested as deposit controlling agent (DCA) f or gasoline. This reaction product is a viscous liquid with density 0,8566 g/ml and kinematic viscosity @40°C of 75,16 cSt, and on its FTIR spectrum shows peak at 3200-3500 cm-1 (amine group). Its anti-deposit performance has been tested using single cylinder gasoline engine, at concentration 300 ppm PIB amine can significantly reduce deposit, comparable to that of the commercial PIBA. The 300 ppm PIB Amine gasoline is also pass gum test, with unwash gum value <75mg/100mL and wash gum value <5 mg/100mL.

AB - Gasoline combustion in an engine always produce carbon particle which then agglomerate, precipitate, and degrade the engine performance. In this research PIB amine, a surfactant having PIB as the hydrocarbon nonpolar tail and TEPA as polar head, is prepared and tested as deposit controlling agent (DCA) f or gasoline. This reaction product is a viscous liquid with density 0,8566 g/ml and kinematic viscosity @40°C of 75,16 cSt, and on its FTIR spectrum shows peak at 3200-3500 cm-1 (amine group). Its anti-deposit performance has been tested using single cylinder gasoline engine, at concentration 300 ppm PIB amine can significantly reduce deposit, comparable to that of the commercial PIBA. The 300 ppm PIB Amine gasoline is also pass gum test, with unwash gum value <75mg/100mL and wash gum value <5 mg/100mL.

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Sukirno, Pitoyo DR, Hastuningtyas SS. Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine. In Kusrini E, Nugraha IGD, editors, 4th International Tropical Renewable Energy Conference, i-TREC 2019. American Institute of Physics Inc. 2020. 0600181. (AIP Conference Proceedings). doi: 10.1063/5.0021655

Synthesis of PIB-amine from polyisobutylene and diamine with its performance test as deposit control additive in one cylinder gasoline engine

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