SYNTHESIS OF NiCo/HIERARCHICAL ZEOLITE CATALYST FOR CATALYTIC CRACKING OF JATROPHA OIL

I. Aziz; D. Gustama; T. Retnaningsih; N. Saridewi; L. Adhani; A. A. Dwiatmoko; M. Ridwan

doi:10.31788/RJC.2022.1537003

SYNTHESIS OF NiCo/HIERARCHICAL ZEOLITE CATALYST FOR CATALYTIC CRACKING OF JATROPHA OIL

I. Aziz, D. Gustama, T. Retnaningsih, N. Saridewi, L. Adhani, A. A. Dwiatmoko, M. Ridwan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Research on a bimetallic NiCo catalyst synthesis was carried out using hierarchical zeolite support (NiCo/HZ). This study aims to determine the effect of the NiCo on characterization and catalyst activity in the catalytic cracking of jatropha oil. The catalyst was characterized using XRD, XRF, SAA, and NH₃-TPD. Its catalytic activity was measured at 375 °C, with a catalyst concentration of 5% w/v for 2 hours. The liquid product was analyzed using GCMS. XRD spectrum of NiCo/HZ showed that the crystalline phase of Ni and Co has one peak at 2θ = 44.2° and 2θ = 44.6°, respectively. Generally, the impregnation of NiCo metals improves the catalyst characteristics, mainly the pore diameter and acidity. NiCo/HZ catalyst with a metal ratio of Ni and Co of 8:2 exhibits the best catalytic activity. It obtains a hydrocarbons yield of 77.45%, with a gasoline selectivity of 82.72%, kerosene of 4.09%, and diesel of 13.18%.

Original language	English
Pages (from-to)	2026-2031
Number of pages	6
Journal	Rasayan Journal of Chemistry
Volume	15
Issue number	3
DOIs	https://doi.org/10.31788/RJC.2022.1537003
Publication status	Published - Jul 2022

Keywords

Catalytic Cracking
Gasoline
Hierarchical Zeolite
Jatropha Oil
NiCo/HZ

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10.31788/RJC.2022.1537003

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@article{eea46b3c61914b329088d78af082e5c4,

title = "SYNTHESIS OF NiCo/HIERARCHICAL ZEOLITE CATALYST FOR CATALYTIC CRACKING OF JATROPHA OIL",

abstract = "Research on a bimetallic NiCo catalyst synthesis was carried out using hierarchical zeolite support (NiCo/HZ). This study aims to determine the effect of the NiCo on characterization and catalyst activity in the catalytic cracking of jatropha oil. The catalyst was characterized using XRD, XRF, SAA, and NH3-TPD. Its catalytic activity was measured at 375 °C, with a catalyst concentration of 5% w/v for 2 hours. The liquid product was analyzed using GCMS. XRD spectrum of NiCo/HZ showed that the crystalline phase of Ni and Co has one peak at 2θ = 44.2° and 2θ = 44.6°, respectively. Generally, the impregnation of NiCo metals improves the catalyst characteristics, mainly the pore diameter and acidity. NiCo/HZ catalyst with a metal ratio of Ni and Co of 8:2 exhibits the best catalytic activity. It obtains a hydrocarbons yield of 77.45%, with a gasoline selectivity of 82.72%, kerosene of 4.09%, and diesel of 13.18%.",

keywords = "Catalytic Cracking, Gasoline, Hierarchical Zeolite, Jatropha Oil, NiCo/HZ",

author = "I. Aziz and D. Gustama and T. Retnaningsih and N. Saridewi and L. Adhani and Dwiatmoko, {A. A.} and M. Ridwan",

note = "Funding Information: The impregnation of NiCo metals on hierarchical zeolites (NiCo/HZ) was successfully carried out. Metal impregnation enhanced the catalyst characteristics in general. The catalytic activity escalated with the increasing NiCo ratio. NiCo catalyst (8:2) yielded 77.45% with selectivity for gasoline at 82.72%, kerosene at 4.09%, and diesel fuel at 13.18%. It stipulates that the NiCo/HZ has good catalytic activity in the conversion of jatropha oil into biofuels. ACKNOWLEDGEMENT The author would like to thank Syarif Hidayatullah State Islamic University for funding this research in 2020. Moreover, the Research Center for Advanced Chemistry, (BRIN) Serpong facilitates the catalyst reduction process. Publisher Copyright: {\textcopyright} 2022, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.",

year = "2022",

month = jul,

doi = "10.31788/RJC.2022.1537003",

language = "English",

volume = "15",

pages = "2026--2031",

journal = "Rasayan Journal of Chemistry",

issn = "0974-1496",

publisher = "Rasayan Journal",

number = "3",

}

TY - JOUR

T1 - SYNTHESIS OF NiCo/HIERARCHICAL ZEOLITE CATALYST FOR CATALYTIC CRACKING OF JATROPHA OIL

AU - Aziz, I.

AU - Gustama, D.

AU - Retnaningsih, T.

AU - Saridewi, N.

AU - Adhani, L.

AU - Dwiatmoko, A. A.

AU - Ridwan, M.

N1 - Funding Information: The impregnation of NiCo metals on hierarchical zeolites (NiCo/HZ) was successfully carried out. Metal impregnation enhanced the catalyst characteristics in general. The catalytic activity escalated with the increasing NiCo ratio. NiCo catalyst (8:2) yielded 77.45% with selectivity for gasoline at 82.72%, kerosene at 4.09%, and diesel fuel at 13.18%. It stipulates that the NiCo/HZ has good catalytic activity in the conversion of jatropha oil into biofuels. ACKNOWLEDGEMENT The author would like to thank Syarif Hidayatullah State Islamic University for funding this research in 2020. Moreover, the Research Center for Advanced Chemistry, (BRIN) Serpong facilitates the catalyst reduction process. Publisher Copyright: © 2022, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.

PY - 2022/7

Y1 - 2022/7

N2 - Research on a bimetallic NiCo catalyst synthesis was carried out using hierarchical zeolite support (NiCo/HZ). This study aims to determine the effect of the NiCo on characterization and catalyst activity in the catalytic cracking of jatropha oil. The catalyst was characterized using XRD, XRF, SAA, and NH3-TPD. Its catalytic activity was measured at 375 °C, with a catalyst concentration of 5% w/v for 2 hours. The liquid product was analyzed using GCMS. XRD spectrum of NiCo/HZ showed that the crystalline phase of Ni and Co has one peak at 2θ = 44.2° and 2θ = 44.6°, respectively. Generally, the impregnation of NiCo metals improves the catalyst characteristics, mainly the pore diameter and acidity. NiCo/HZ catalyst with a metal ratio of Ni and Co of 8:2 exhibits the best catalytic activity. It obtains a hydrocarbons yield of 77.45%, with a gasoline selectivity of 82.72%, kerosene of 4.09%, and diesel of 13.18%.

AB - Research on a bimetallic NiCo catalyst synthesis was carried out using hierarchical zeolite support (NiCo/HZ). This study aims to determine the effect of the NiCo on characterization and catalyst activity in the catalytic cracking of jatropha oil. The catalyst was characterized using XRD, XRF, SAA, and NH3-TPD. Its catalytic activity was measured at 375 °C, with a catalyst concentration of 5% w/v for 2 hours. The liquid product was analyzed using GCMS. XRD spectrum of NiCo/HZ showed that the crystalline phase of Ni and Co has one peak at 2θ = 44.2° and 2θ = 44.6°, respectively. Generally, the impregnation of NiCo metals improves the catalyst characteristics, mainly the pore diameter and acidity. NiCo/HZ catalyst with a metal ratio of Ni and Co of 8:2 exhibits the best catalytic activity. It obtains a hydrocarbons yield of 77.45%, with a gasoline selectivity of 82.72%, kerosene of 4.09%, and diesel of 13.18%.

KW - Catalytic Cracking

KW - Gasoline

KW - Hierarchical Zeolite

KW - Jatropha Oil

KW - NiCo/HZ

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U2 - 10.31788/RJC.2022.1537003

DO - 10.31788/RJC.2022.1537003

M3 - Article

AN - SCOPUS:85138744553

SN - 0974-1496

VL - 15

SP - 2026

EP - 2031

JO - Rasayan Journal of Chemistry

JF - Rasayan Journal of Chemistry

IS - 3

ER -

SYNTHESIS OF NiCo/HIERARCHICAL ZEOLITE CATALYST FOR CATALYTIC CRACKING OF JATROPHA OIL

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Keywords

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