TY - JOUR
T1 - Synthesis of kemiri sunan (reutealis trisperma (blanco) airy shaw) H-FAME through partially hydrogenation using Ni/C catalyst to increase oxidation stability
AU - Ramayeni, E.
AU - Susanto, B. H.
AU - Pratama, D. F.
N1 - Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2018/1/25
Y1 - 2018/1/25
N2 - Hydrogenated FAME (H-FAME) synthesis of Kemiri Sunan (Reutealis Trisperma (Blanco) Airy Shaw) using Nickel/Carbon catalyst is one of the methods to improve the oxidation stability of Kemiri Sunan biodiesel. The partial hydrogenation reaction breaks the unsaturated bond on FAME (Fatty Acid Methyl Ester), which is a key component of the determination of oxidative properties. Changes in FAME composition by partial hydrogenation reaction are predicted to change the oxidation stability, so it does not cause deposits that can damage the diesel engine injection system, pump system, and storage tank. Partial hydrogenation reaction is under conditions of 120 °C and 6 bars with 100:1, 100:5, 100:10 % wt catalyst in the stirred semi-batch autoclave reactor. H-FAME synthesis with 100:5 % wt Ni/C catalyst can decrease the iodine number which is the empirical measure of the number of unsaturated bonds from 166.77 to 155.64 (g-I2/100 g) with an increase of oxidation stability from 650 to 665 minutes.
AB - Hydrogenated FAME (H-FAME) synthesis of Kemiri Sunan (Reutealis Trisperma (Blanco) Airy Shaw) using Nickel/Carbon catalyst is one of the methods to improve the oxidation stability of Kemiri Sunan biodiesel. The partial hydrogenation reaction breaks the unsaturated bond on FAME (Fatty Acid Methyl Ester), which is a key component of the determination of oxidative properties. Changes in FAME composition by partial hydrogenation reaction are predicted to change the oxidation stability, so it does not cause deposits that can damage the diesel engine injection system, pump system, and storage tank. Partial hydrogenation reaction is under conditions of 120 °C and 6 bars with 100:1, 100:5, 100:10 % wt catalyst in the stirred semi-batch autoclave reactor. H-FAME synthesis with 100:5 % wt Ni/C catalyst can decrease the iodine number which is the empirical measure of the number of unsaturated bonds from 166.77 to 155.64 (g-I2/100 g) with an increase of oxidation stability from 650 to 665 minutes.
UR - http://www.scopus.com/inward/record.url?scp=85041697019&partnerID=8YFLogxK
U2 - 10.1088/1755-1315/105/1/012055
DO - 10.1088/1755-1315/105/1/012055
M3 - Conference article
AN - SCOPUS:85041697019
SN - 1755-1307
VL - 105
JO - IOP Conference Series: Earth and Environmental Science
JF - IOP Conference Series: Earth and Environmental Science
IS - 1
M1 - 012055
T2 - 2nd International Tropical Renewable Energy Conference, i-TREC 2017
Y2 - 3 October 2017 through 4 October 2017
ER -