Synthesis of imidazoline-linoleic derivative using MAOS (Microwave Assisted Organic Synthesis) method and its activity as corrosion inhibitor towards carbon steel

A. Yuniastuti, D. U.C. Rahayu, D. A. Nurani, Y. K. Krisnandi, E. Budianto

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Citations (Scopus)

Abstract

In this research, imidazoline-linoleic derivative from triethylenetetramine (TETA) and linoleic acid (LNA) were successfully synthesized with solvent free using MAOS (Microwave Assisted Organic Synthesis) method in variation of reaction time. TETA-LNA imidazoline was in mixture with imidazoline-oleic derivative with the optimum mass of 1.70 g at 9 min reaction time. Furthermore, TETA-LNA imidazoline structure had been confirmed using FTIR, UV-Vis, and LC-MS/MS spectral data. Its activity as corrosion inhibitor was measured by varying TETA-LNA concentration in 1 % NaCl using cyclic voltammetry then processed using Tafel polarization method to obtain percentage of inhibition efficiency (% IE). The highest corrosion inhibitor activity was achieved at 500 ppm with % IE of 89.3 %. It can be suggested that imidazoline-linoleic derivatives can be used as corrosion inhibitor towards carbon steel.

Original languageEnglish
Title of host publicationProceedings of the 4th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2018
EditorsTerry Mart, Djoko Triyono, Ivandini T. Anggraningrum
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735419155
DOIs
Publication statusPublished - 4 Nov 2019
Event4th International Symposium on Current Progress in Mathematics and Sciences 2018, ISCPMS 2018 - Depok, Indonesia
Duration: 30 Oct 201831 Oct 2018

Publication series

NameAIP Conference Proceedings
Volume2168
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference4th International Symposium on Current Progress in Mathematics and Sciences 2018, ISCPMS 2018
Country/TerritoryIndonesia
CityDepok
Period30/10/1831/10/18

Keywords

  • corrosion inhibitor
  • Imidazoline
  • linoleic acid
  • MAOS
  • triethylenetetramine

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