TY - JOUR
T1 - Synthesis of green diesel through hydrolysis and hydrodeoxygenation reaction from waste cooking oil using NiMo/Al2O3 catalyst
AU - Putri, R. U.
AU - Susanto, Bambang Heru
AU - Pratama, D. F.
AU - Prakasa, M. B.
N1 - Funding Information:
Director of Research and Community Service through International Indexed Publication Grant for Student Thesis (PITTA) Universitas Indonesia 2017 is acknowledged for the financial support to carry out the present study.
Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2018/1/25
Y1 - 2018/1/25
N2 - Green diesel is a second generation of biofuel that has a potential to answer the energy needs in Indonesia, also in the world. The reactions used to produce green diesel are hydrolysis and hydrodeoxygenation by using NiMo/Al2O3 catalyst. Hydrolysis will change the triglycerides in the raw material, which is waste cooking oil into free fatty acids (FFA) and then converted into green diesel through hydrodeoxygenation. Hydrolysis of waste cooking oil carried out at temperature of 200°C and pressure of 16 bar for 3 hours with water and oil volume ratio of 1:1. FFA product of hydrolysis is as much as 73.89%. For hydrodeoxygenation, variation in operating condition used are 375°C with pressure of 12 bar and 400°C with pressure of 15 bar. Characterizations of green diesel have shown that both of hydrodeoxygenation products have met the specifications of diesel, except the acid number with optimum operating condition at 400°C and pressure of 15 bar. These conditions with NiMo/Al2O3 activated led to dominant yield of 68.87% of diesel fraction, selectivity of 69.58%, and conversion of 82.15%.
AB - Green diesel is a second generation of biofuel that has a potential to answer the energy needs in Indonesia, also in the world. The reactions used to produce green diesel are hydrolysis and hydrodeoxygenation by using NiMo/Al2O3 catalyst. Hydrolysis will change the triglycerides in the raw material, which is waste cooking oil into free fatty acids (FFA) and then converted into green diesel through hydrodeoxygenation. Hydrolysis of waste cooking oil carried out at temperature of 200°C and pressure of 16 bar for 3 hours with water and oil volume ratio of 1:1. FFA product of hydrolysis is as much as 73.89%. For hydrodeoxygenation, variation in operating condition used are 375°C with pressure of 12 bar and 400°C with pressure of 15 bar. Characterizations of green diesel have shown that both of hydrodeoxygenation products have met the specifications of diesel, except the acid number with optimum operating condition at 400°C and pressure of 15 bar. These conditions with NiMo/Al2O3 activated led to dominant yield of 68.87% of diesel fraction, selectivity of 69.58%, and conversion of 82.15%.
UR - http://www.scopus.com/inward/record.url?scp=85041676154&partnerID=8YFLogxK
U2 - 10.1088/1755-1315/105/1/012051
DO - 10.1088/1755-1315/105/1/012051
M3 - Conference article
AN - SCOPUS:85041676154
VL - 105
JO - IOP Conference Series: Earth and Environmental Science
JF - IOP Conference Series: Earth and Environmental Science
SN - 1755-1307
IS - 1
M1 - 012051
T2 - 2nd International Tropical Renewable Energy Conference, i-TREC 2017
Y2 - 3 October 2017 through 4 October 2017
ER -