Synthesis and characterization of ZnO/Au and ZnO/AuAg mesoflower composites for photoelectrochemical water-splitting applications

A. P. Mentari, V. Fauzia, M. Khotib

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Photoelectrochemical (PEC) water splitting is among of the greatest assuring methods in producing hydrogen. One of the alternative semiconductor materials used as a photoanode for water-splitting applications is ZnO. However, this compound has several drawbacks that can be overcome by combining it with noble metal particles. In this study, ZnO nanorods (NRs) were synthesized using the hydrothermal method and then decorated with AuAg mesoflowers (MFs) synthesized by the wet chemical method. A linear sweep voltammogram (LSV) measurement under visible light and AM 1.5 G shows that the ZnO/AuAg MFs produced the highest photocurrent in the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) with the highest efficiency, of 0.034 % at a voltage of 0.874V vs reversible hydrogen electrode (RHE). The AuAg MFs may act as electron donors, injecting electrons into the ZnO conduction band to increase the photocurrent.

Original languageEnglish
Title of host publicationProceedings of the 6th International Symposium on Current Progress in Mathematics and Sciences 2020, ISCPMS 2020
EditorsTribidasari A. Ivandini, David G. Churchill, Youngil Lee, Yatimah Binti Alias, Chris Margules
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735441132
DOIs
Publication statusPublished - 23 Jul 2021
Event6th International Symposium on Current Progress in Mathematics and Sciences 2020, ISCPMS 2020 - Depok, Indonesia
Duration: 27 Oct 202028 Oct 2020

Publication series

NameAIP Conference Proceedings
Volume2374
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference6th International Symposium on Current Progress in Mathematics and Sciences 2020, ISCPMS 2020
Country/TerritoryIndonesia
CityDepok
Period27/10/2028/10/20

Keywords

  • AuAg mesoflowers
  • photoelectrochemical water splitting
  • plasmonic effect
  • ZnO

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