Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst

A. Zulys; D. Asrianti; J. Gunlazuardi

doi:10.1063/5.0005001

Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

5 Citations (Scopus)

Abstract

Nickel-Metal Organic Frameworks (Ni-MOFs-ptc) has been successfully synthesized based on perylene 3,4,9,10-tetracarboxylic dyes as linker organic using the solvothermal method. Chromophoric linker in ptc structure is utilized to obtain MOFs with light harvesting properties.. In this study, parameters variations in the synthesis of Ni- MOFs-ptc were carried out through time reaction. The absence of absorption at wavenumber 1700 cm^-1 as vibration stretching v(C=O) from Ni-MOFs-ptc, indicates that the oxygen atom from ligand can coordinate with the Nickel metal ion. This indicates that Ni-MOFs-ptc has been successfully formed. X-Ray diffraction of Ni-MOFs-ptc exhibits sharp and high intensity peak which indicates high crystallinity Ni-MOFs-ptc. Ni-MOFs-ptc possesses a HOMO-LUMO band gap of 2,41 eV determined by UV-Vis spectroscopy with an absorption edge at 514 nm, which present effective photocatalytic activity for hydrogen production under UV-Visible irradiation.

Original language	English
Title of host publication	8th International Conference of the Indonesian Chemical Society, ICICS 2019
Editors	Mohamad Rafi, Rudi Heryanto, Wulan Tri Wahyuni
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735420021
DOIs	https://doi.org/10.1063/5.0005001
Publication status	Published - 4 Jun 2020
Event	8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019 - Bogor, Indonesia Duration: 6 Aug 2019 → 7 Aug 2019

Publication series

Name	AIP Conference Proceedings
Volume	2243
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019
Country/Territory	Indonesia
City	Bogor
Period	6/08/19 → 7/08/19

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

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10.1063/5.0005001

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Zulys, A., Asrianti, D., & Gunlazuardi, J. (2020). Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst. In M. Rafi, R. Heryanto, & W. T. Wahyuni (Eds.), 8th International Conference of the Indonesian Chemical Society, ICICS 2019 Article 020035 (AIP Conference Proceedings; Vol. 2243). American Institute of Physics Inc.. https://doi.org/10.1063/5.0005001

Zulys, A. ; Asrianti, D. ; Gunlazuardi, J. / Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst. 8th International Conference of the Indonesian Chemical Society, ICICS 2019. editor / Mohamad Rafi ; Rudi Heryanto ; Wulan Tri Wahyuni. American Institute of Physics Inc., 2020. (AIP Conference Proceedings).

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title = "Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst",

abstract = "Nickel-Metal Organic Frameworks (Ni-MOFs-ptc) has been successfully synthesized based on perylene 3,4,9,10-tetracarboxylic dyes as linker organic using the solvothermal method. Chromophoric linker in ptc structure is utilized to obtain MOFs with light harvesting properties.. In this study, parameters variations in the synthesis of Ni- MOFs-ptc were carried out through time reaction. The absence of absorption at wavenumber 1700 cm-1 as vibration stretching v(C=O) from Ni-MOFs-ptc, indicates that the oxygen atom from ligand can coordinate with the Nickel metal ion. This indicates that Ni-MOFs-ptc has been successfully formed. X-Ray diffraction of Ni-MOFs-ptc exhibits sharp and high intensity peak which indicates high crystallinity Ni-MOFs-ptc. Ni-MOFs-ptc possesses a HOMO-LUMO band gap of 2,41 eV determined by UV-Vis spectroscopy with an absorption edge at 514 nm, which present effective photocatalytic activity for hydrogen production under UV-Visible irradiation.",

author = "A. Zulys and D. Asrianti and J. Gunlazuardi",

note = "Publisher Copyright: {\textcopyright} 2020 Author(s).; 8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019 ; Conference date: 06-08-2019 Through 07-08-2019",

year = "2020",

month = jun,

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doi = "10.1063/5.0005001",

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Zulys, A , Asrianti, D & Gunlazuardi, J 2020, Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst. in M Rafi, R Heryanto & WT Wahyuni (eds), 8th International Conference of the Indonesian Chemical Society, ICICS 2019., 020035, AIP Conference Proceedings, vol. 2243, American Institute of Physics Inc., 8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019, Bogor, Indonesia, 6/08/19. https://doi.org/10.1063/5.0005001

Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst. / Zulys, A.; Asrianti, D.; Gunlazuardi, J.
8th International Conference of the Indonesian Chemical Society, ICICS 2019. ed. / Mohamad Rafi; Rudi Heryanto; Wulan Tri Wahyuni. American Institute of Physics Inc., 2020. 020035 (AIP Conference Proceedings; Vol. 2243).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst

AU - Zulys, A.

AU - Asrianti, D.

AU - Gunlazuardi, J.

PY - 2020/6/4

Y1 - 2020/6/4

N2 - Nickel-Metal Organic Frameworks (Ni-MOFs-ptc) has been successfully synthesized based on perylene 3,4,9,10-tetracarboxylic dyes as linker organic using the solvothermal method. Chromophoric linker in ptc structure is utilized to obtain MOFs with light harvesting properties.. In this study, parameters variations in the synthesis of Ni- MOFs-ptc were carried out through time reaction. The absence of absorption at wavenumber 1700 cm-1 as vibration stretching v(C=O) from Ni-MOFs-ptc, indicates that the oxygen atom from ligand can coordinate with the Nickel metal ion. This indicates that Ni-MOFs-ptc has been successfully formed. X-Ray diffraction of Ni-MOFs-ptc exhibits sharp and high intensity peak which indicates high crystallinity Ni-MOFs-ptc. Ni-MOFs-ptc possesses a HOMO-LUMO band gap of 2,41 eV determined by UV-Vis spectroscopy with an absorption edge at 514 nm, which present effective photocatalytic activity for hydrogen production under UV-Visible irradiation.

AB - Nickel-Metal Organic Frameworks (Ni-MOFs-ptc) has been successfully synthesized based on perylene 3,4,9,10-tetracarboxylic dyes as linker organic using the solvothermal method. Chromophoric linker in ptc structure is utilized to obtain MOFs with light harvesting properties.. In this study, parameters variations in the synthesis of Ni- MOFs-ptc were carried out through time reaction. The absence of absorption at wavenumber 1700 cm-1 as vibration stretching v(C=O) from Ni-MOFs-ptc, indicates that the oxygen atom from ligand can coordinate with the Nickel metal ion. This indicates that Ni-MOFs-ptc has been successfully formed. X-Ray diffraction of Ni-MOFs-ptc exhibits sharp and high intensity peak which indicates high crystallinity Ni-MOFs-ptc. Ni-MOFs-ptc possesses a HOMO-LUMO band gap of 2,41 eV determined by UV-Vis spectroscopy with an absorption edge at 514 nm, which present effective photocatalytic activity for hydrogen production under UV-Visible irradiation.

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DO - 10.1063/5.0005001

M3 - Conference contribution

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T3 - AIP Conference Proceedings

BT - 8th International Conference of the Indonesian Chemical Society, ICICS 2019

A2 - Rafi, Mohamad

A2 - Heryanto, Rudi

A2 - Wahyuni, Wulan Tri

PB - American Institute of Physics Inc.

T2 - 8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019

Y2 - 6 August 2019 through 7 August 2019

ER -

Zulys A , Asrianti D , Gunlazuardi J. Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst. In Rafi M, Heryanto R, Wahyuni WT, editors, 8th International Conference of the Indonesian Chemical Society, ICICS 2019. American Institute of Physics Inc. 2020. 020035. (AIP Conference Proceedings). doi: 10.1063/5.0005001

Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst

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