Synthesis and characterization of metal organic frameworks based on nickel and perylene dyes as water splitting photocatalyst

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Nickel-Metal Organic Frameworks (Ni-MOFs-ptc) has been successfully synthesized based on perylene 3,4,9,10-tetracarboxylic dyes as linker organic using the solvothermal method. Chromophoric linker in ptc structure is utilized to obtain MOFs with light harvesting properties.. In this study, parameters variations in the synthesis of Ni- MOFs-ptc were carried out through time reaction. The absence of absorption at wavenumber 1700 cm-1 as vibration stretching v(C=O) from Ni-MOFs-ptc, indicates that the oxygen atom from ligand can coordinate with the Nickel metal ion. This indicates that Ni-MOFs-ptc has been successfully formed. X-Ray diffraction of Ni-MOFs-ptc exhibits sharp and high intensity peak which indicates high crystallinity Ni-MOFs-ptc. Ni-MOFs-ptc possesses a HOMO-LUMO band gap of 2,41 eV determined by UV-Vis spectroscopy with an absorption edge at 514 nm, which present effective photocatalytic activity for hydrogen production under UV-Visible irradiation.

Original languageEnglish
Title of host publication8th International Conference of the Indonesian Chemical Society, ICICS 2019
EditorsMohamad Rafi, Rudi Heryanto, Wulan Tri Wahyuni
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735420021
DOIs
Publication statusPublished - 4 Jun 2020
Event8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019 - Bogor, Indonesia
Duration: 6 Aug 20197 Aug 2019

Publication series

NameAIP Conference Proceedings
Volume2243
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference8th International Conference of the Indonesian Chemical Society 2019, ICICS 2019
CountryIndonesia
CityBogor
Period6/08/197/08/19

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