TY - JOUR
T1 - Synthesis and characterization of a novel microporous lanthanide based metal-organic framework (MOF) using napthalenedicarboxylate acid
AU - Nasruddin,
AU - Zulys, A.
AU - Yulia, Fayza
AU - Buhori, Achmad
AU - Muhadzib, Naufal
AU - Ghiyats, Muhammad
AU - Saha, Bidyut B.
N1 - Funding Information:
The authors gratefully acknowledge for the Ministry of Research, Technology, and Higher Education, Republic of Indonesia through the World Class Professor Program Scheme – A (number T/41/D2.3/KK.04.05/2019), Osaka Gas Foundation and Hibah Q1Q2 2109 No. NKB-0316/UN2.R3.1/HKP.05.00/2019 from DRPM Universitas Indonesia.
Publisher Copyright:
© 2020 The Author(s).
PY - 2020
Y1 - 2020
N2 - A novel metal-organic framework based on naphthalenedicarboxylic acid is described. By solvothermal reaction method, 2,6-Naphthalenedicarboxylic acid, existing organic ligands that have never been used to support La-MOFs, was synthesized using acetic acid as the solvent and lanthanum nitrate hexahydrate as a metal source. So far, this type of metal-organic framework based lanthanum ion has not been investigated before. La-NDC MOFs were characterized to determine its functional groups contained in La-MOFs, morphology and particle size, crystallinity, optical and thermal stability by SEM (Scanning Electron Microscopy), FTIR (Fourier transform infrared) spectroscopy, XRD (X-ray Diffraction), UV-vis and TGA (thermogravimetric analysis) sequencely. The adsorption/desorption isotherms of N2 were measured at 77.4 K to know the specific surface area and pore volume of La-NDC MOF. BET (Brunauer-Emmet-Teller) equation was also applied to calculate the surface area of compounds.
AB - A novel metal-organic framework based on naphthalenedicarboxylic acid is described. By solvothermal reaction method, 2,6-Naphthalenedicarboxylic acid, existing organic ligands that have never been used to support La-MOFs, was synthesized using acetic acid as the solvent and lanthanum nitrate hexahydrate as a metal source. So far, this type of metal-organic framework based lanthanum ion has not been investigated before. La-NDC MOFs were characterized to determine its functional groups contained in La-MOFs, morphology and particle size, crystallinity, optical and thermal stability by SEM (Scanning Electron Microscopy), FTIR (Fourier transform infrared) spectroscopy, XRD (X-ray Diffraction), UV-vis and TGA (thermogravimetric analysis) sequencely. The adsorption/desorption isotherms of N2 were measured at 77.4 K to know the specific surface area and pore volume of La-NDC MOF. BET (Brunauer-Emmet-Teller) equation was also applied to calculate the surface area of compounds.
KW - Lanthanide
KW - Lanthanum
KW - Metal-organic frameworks (MOFs)
KW - NDC
UR - http://www.scopus.com/inward/record.url?scp=85091729224&partnerID=8YFLogxK
U2 - 10.1016/j.jmrt.2020.05.015
DO - 10.1016/j.jmrt.2020.05.015
M3 - Article
AN - SCOPUS:85091729224
SN - 2238-7854
VL - 9
SP - 7409
EP - 7417
JO - Journal of Materials Research and Technology
JF - Journal of Materials Research and Technology
IS - 4
ER -