Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Bayu Ardiansah, Hiroki Tanimoto, Takenori Tomohiro, Tsumoru Morimoto, Kiyomi Kakiuchi

Research output: Contribution to journalArticlepeer-review

Abstract

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

Original languageEnglish
Pages (from-to)8738-8741
Number of pages4
JournalChemical Communications
Volume57
Issue number70
DOIs
Publication statusPublished - 11 Sep 2021

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