Lithium-Ion Battery (LIB) has been widely utilized as this battery show excellent performance to be used as power source in our life. Li4Ti5O12 (LTO) is one of the anode materials of Lithium-Ion Battery which possess excellent electrochemical performance because of its zero-strain characteristic. However, LTO performance is limited by its low specific capacity (175 mAh g-1) and cycle stability. In this study, Solid-state synthesis method was used to synthesize LTO using LiOH and TiO2 powder as precursors. Addition of Silicon Carbide (SiC) was done using wet ball mill method to enhance its capacity and cycle stability. To determine the effect of SiC addition on these composites, various composition of SiC were carried out at 0 wt.%.; 4 wt.%; 7 wt.%; and 10 wt.%. Experimental results showed that LTO/SiC composites were synthesized successfully, the X-ray Diffraction (XRD) characterization exhibits the formation of LTO/SiC as a major product. Moreover, Electrochemical Impedance Spectroscopy (EIS) performance testing showed that LTO/SiC 4 % possess highest electrical conductivity which is indicated by its lowest resistivity compared to other samples.