Study on performance of SiC addition to Li4Ti5O12composite as an anode material synthesized through solid-state reaction for lithium-ion battery

Said Firdaus; Anne Z. Syahrial; A. Subhan; Bambang Priyono

doi:10.1063/5.0001709

Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery

Said Firdaus, Anne Z. Syahrial, A. Subhan, Bambang Priyono

Department of Metallurgical and Material Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

Lithium-Ion Battery (LIB) has been widely utilized as this battery show excellent performance to be used as power source in our life. Li4Ti5O12 (LTO) is one of the anode materials of Lithium-Ion Battery which possess excellent electrochemical performance because of its zero-strain characteristic. However, LTO performance is limited by its low specific capacity (175 mAh g-1) and cycle stability. In this study, Solid-state synthesis method was used to synthesize LTO using LiOH and TiO2 powder as precursors. Addition of Silicon Carbide (SiC) was done using wet ball mill method to enhance its capacity and cycle stability. To determine the effect of SiC addition on these composites, various composition of SiC were carried out at 0 wt.%.; 4 wt.%; 7 wt.%; and 10 wt.%. Experimental results showed that LTO/SiC composites were synthesized successfully, the X-ray Diffraction (XRD) characterization exhibits the formation of LTO/SiC as a major product. Moreover, Electrochemical Impedance Spectroscopy (EIS) performance testing showed that LTO/SiC 4 % possess highest electrical conductivity which is indicated by its lowest resistivity compared to other samples.

Original language	English
Title of host publication	Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019
Subtitle of host publication	Exploring New Innovation in Metallurgy and Materials
Editors	Nono Darsono, Yudi Nugraha Thaha, Aga Ridhova, Ahmad Rhamdani, Muhammad Satrio Utomo, Faried Miftahur Ridlo, Mukhlis Agung Prasetyo
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735419919
DOIs	https://doi.org/10.1063/5.0001709
Publication status	Published - 21 Apr 2020
Event	3rd International Seminar on Metallurgy and Materials: Exploring New Innovation in Metallurgy and Materials, ISMM 2019 - Tangerang Selatan, Indonesia Duration: 23 Oct 2019 → 24 Oct 2019

Publication series

Name	AIP Conference Proceedings
Volume	2232
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	3rd International Seminar on Metallurgy and Materials: Exploring New Innovation in Metallurgy and Materials, ISMM 2019
Country/Territory	Indonesia
City	Tangerang Selatan
Period	23/10/19 → 24/10/19

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1063/5.0001709

Cite this

Firdaus, S., Syahrial, A. Z., Subhan, A., & Priyono, B. (2020). Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery. In N. Darsono, Y. N. Thaha, A. Ridhova, A. Rhamdani, M. S. Utomo, F. M. Ridlo, & M. A. Prasetyo (Eds.), Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019: Exploring New Innovation in Metallurgy and Materials Article 030002 (AIP Conference Proceedings; Vol. 2232). American Institute of Physics Inc.. https://doi.org/10.1063/5.0001709

Firdaus, Said ; Syahrial, Anne Z. ; Subhan, A. et al. / Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery. Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019: Exploring New Innovation in Metallurgy and Materials. editor / Nono Darsono ; Yudi Nugraha Thaha ; Aga Ridhova ; Ahmad Rhamdani ; Muhammad Satrio Utomo ; Faried Miftahur Ridlo ; Mukhlis Agung Prasetyo. American Institute of Physics Inc., 2020. (AIP Conference Proceedings).

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title = "Study on performance of SiC addition to Li4Ti5O12composite as an anode material synthesized through solid-state reaction for lithium-ion battery",

abstract = "Lithium-Ion Battery (LIB) has been widely utilized as this battery show excellent performance to be used as power source in our life. Li4Ti5O12 (LTO) is one of the anode materials of Lithium-Ion Battery which possess excellent electrochemical performance because of its zero-strain characteristic. However, LTO performance is limited by its low specific capacity (175 mAh g-1) and cycle stability. In this study, Solid-state synthesis method was used to synthesize LTO using LiOH and TiO2 powder as precursors. Addition of Silicon Carbide (SiC) was done using wet ball mill method to enhance its capacity and cycle stability. To determine the effect of SiC addition on these composites, various composition of SiC were carried out at 0 wt.%.; 4 wt.%; 7 wt.%; and 10 wt.%. Experimental results showed that LTO/SiC composites were synthesized successfully, the X-ray Diffraction (XRD) characterization exhibits the formation of LTO/SiC as a major product. Moreover, Electrochemical Impedance Spectroscopy (EIS) performance testing showed that LTO/SiC 4 % possess highest electrical conductivity which is indicated by its lowest resistivity compared to other samples.",

author = "Said Firdaus and Syahrial, {Anne Z.} and A. Subhan and Bambang Priyono",

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Firdaus, S, Syahrial, AZ, Subhan, A & Priyono, B 2020, Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery. in N Darsono, YN Thaha, A Ridhova, A Rhamdani, MS Utomo, FM Ridlo & MA Prasetyo (eds), Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019: Exploring New Innovation in Metallurgy and Materials., 030002, AIP Conference Proceedings, vol. 2232, American Institute of Physics Inc., 3rd International Seminar on Metallurgy and Materials: Exploring New Innovation in Metallurgy and Materials, ISMM 2019, Tangerang Selatan, Indonesia, 23/10/19. https://doi.org/10.1063/5.0001709

Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery. / Firdaus, Said; Syahrial, Anne Z.; Subhan, A. et al.
Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019: Exploring New Innovation in Metallurgy and Materials. ed. / Nono Darsono; Yudi Nugraha Thaha; Aga Ridhova; Ahmad Rhamdani; Muhammad Satrio Utomo; Faried Miftahur Ridlo; Mukhlis Agung Prasetyo. American Institute of Physics Inc., 2020. 030002 (AIP Conference Proceedings; Vol. 2232).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Subhan, A.

AU - Priyono, Bambang

PY - 2020/4/21

Y1 - 2020/4/21

N2 - Lithium-Ion Battery (LIB) has been widely utilized as this battery show excellent performance to be used as power source in our life. Li4Ti5O12 (LTO) is one of the anode materials of Lithium-Ion Battery which possess excellent electrochemical performance because of its zero-strain characteristic. However, LTO performance is limited by its low specific capacity (175 mAh g-1) and cycle stability. In this study, Solid-state synthesis method was used to synthesize LTO using LiOH and TiO2 powder as precursors. Addition of Silicon Carbide (SiC) was done using wet ball mill method to enhance its capacity and cycle stability. To determine the effect of SiC addition on these composites, various composition of SiC were carried out at 0 wt.%.; 4 wt.%; 7 wt.%; and 10 wt.%. Experimental results showed that LTO/SiC composites were synthesized successfully, the X-ray Diffraction (XRD) characterization exhibits the formation of LTO/SiC as a major product. Moreover, Electrochemical Impedance Spectroscopy (EIS) performance testing showed that LTO/SiC 4 % possess highest electrical conductivity which is indicated by its lowest resistivity compared to other samples.

AB - Lithium-Ion Battery (LIB) has been widely utilized as this battery show excellent performance to be used as power source in our life. Li4Ti5O12 (LTO) is one of the anode materials of Lithium-Ion Battery which possess excellent electrochemical performance because of its zero-strain characteristic. However, LTO performance is limited by its low specific capacity (175 mAh g-1) and cycle stability. In this study, Solid-state synthesis method was used to synthesize LTO using LiOH and TiO2 powder as precursors. Addition of Silicon Carbide (SiC) was done using wet ball mill method to enhance its capacity and cycle stability. To determine the effect of SiC addition on these composites, various composition of SiC were carried out at 0 wt.%.; 4 wt.%; 7 wt.%; and 10 wt.%. Experimental results showed that LTO/SiC composites were synthesized successfully, the X-ray Diffraction (XRD) characterization exhibits the formation of LTO/SiC as a major product. Moreover, Electrochemical Impedance Spectroscopy (EIS) performance testing showed that LTO/SiC 4 % possess highest electrical conductivity which is indicated by its lowest resistivity compared to other samples.

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BT - Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019

A2 - Darsono, Nono

A2 - Thaha, Yudi Nugraha

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Firdaus S, Syahrial AZ, Subhan A, Priyono B. Study on performance of SiC addition to Li₄Ti₅O₁₂composite as an anode material synthesized through solid-state reaction for lithium-ion battery. In Darsono N, Thaha YN, Ridhova A, Rhamdani A, Utomo MS, Ridlo FM, Prasetyo MA, editors, Proceedings of the 3rd International Seminar on Metallurgy and Materials, ISMM 2019: Exploring New Innovation in Metallurgy and Materials. American Institute of Physics Inc. 2020. 030002. (AIP Conference Proceedings). doi: 10.1063/5.0001709