Simultaneous utilization of CO2 and CH4 through dry reforming of methane with Ni–Ce@SiO2 catalyst: Parametric and simulation studies

Intan Clarissa Sophiana; Soen Steven; Arnetta Revieri; Anisa Permatasari; Riezqa Andika; Norikazu Nishiyama; Bambang Heru Susanto

doi:10.1016/j.cscee.2024.101078

Simultaneous utilization of CO₂ and CH₄ through dry reforming of methane with Ni–Ce@SiO₂ catalyst: Parametric and simulation studies

Intan Clarissa Sophiana, Soen Steven, Arnetta Revieri, Anisa Permatasari, Riezqa Andika, Norikazu Nishiyama, Bambang Heru Susanto

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The dry reforming of methane (DRM) can reduce CO₂ and CH₄ simultaneously. This study utilized East Natuna gas fields, composed of 70 % CO₂ and 30 % CH₄, for syngas production via DRM using a Ni–Ce@SiO₂ catalyst. The kinetic parameters employed the Langmuir-Hinshelwood mechanism on the surface reaction as the rate-determining step. The simulation results provided an error margin below 5 %. A CO₂:CH₄ feed ratio of 70:30 at 700^oC achieves higher CH₄ conversion than a 50:50 ratio (97.10 % vs. 79.01 %), yet with lower H₂/CO ratio (0.68 vs. 0.92). Also, higher temperatures impact shorter reactor lengths and swifter times to reach stable conversion.

Original language	English
Article number	101078
Journal	Case Studies in Chemical and Environmental Engineering
Volume	11
DOIs	https://doi.org/10.1016/j.cscee.2024.101078
Publication status	Published - Jun 2025

Keywords

Greenhouse gas
Kinetic parameter
Langmuir-hinshelwood
Nickel
Syngas

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10.1016/j.cscee.2024.101078

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title = "Simultaneous utilization of CO2 and CH4 through dry reforming of methane with Ni–Ce@SiO2 catalyst: Parametric and simulation studies",

abstract = "The dry reforming of methane (DRM) can reduce CO2 and CH4 simultaneously. This study utilized East Natuna gas fields, composed of 70 % CO2 and 30 % CH4, for syngas production via DRM using a Ni–Ce@SiO2 catalyst. The kinetic parameters employed the Langmuir-Hinshelwood mechanism on the surface reaction as the rate-determining step. The simulation results provided an error margin below 5 %. A CO2:CH4 feed ratio of 70:30 at 700oC achieves higher CH4 conversion than a 50:50 ratio (97.10 % vs. 79.01 %), yet with lower H2/CO ratio (0.68 vs. 0.92). Also, higher temperatures impact shorter reactor lengths and swifter times to reach stable conversion.",

keywords = "Greenhouse gas, Kinetic parameter, Langmuir-hinshelwood, Nickel, Syngas",

author = "Sophiana, {Intan Clarissa} and Soen Steven and Arnetta Revieri and Anisa Permatasari and Riezqa Andika and Norikazu Nishiyama and Susanto, {Bambang Heru}",

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doi = "10.1016/j.cscee.2024.101078",

language = "English",

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journal = "Case Studies in Chemical and Environmental Engineering",

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T2 - Parametric and simulation studies

AU - Sophiana, Intan Clarissa

AU - Steven, Soen

AU - Revieri, Arnetta

AU - Permatasari, Anisa

AU - Andika, Riezqa

AU - Nishiyama, Norikazu

AU - Susanto, Bambang Heru

PY - 2025/6

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AB - The dry reforming of methane (DRM) can reduce CO2 and CH4 simultaneously. This study utilized East Natuna gas fields, composed of 70 % CO2 and 30 % CH4, for syngas production via DRM using a Ni–Ce@SiO2 catalyst. The kinetic parameters employed the Langmuir-Hinshelwood mechanism on the surface reaction as the rate-determining step. The simulation results provided an error margin below 5 %. A CO2:CH4 feed ratio of 70:30 at 700oC achieves higher CH4 conversion than a 50:50 ratio (97.10 % vs. 79.01 %), yet with lower H2/CO ratio (0.68 vs. 0.92). Also, higher temperatures impact shorter reactor lengths and swifter times to reach stable conversion.

KW - Greenhouse gas

KW - Kinetic parameter

KW - Langmuir-hinshelwood

KW - Nickel

KW - Syngas

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ER -

Simultaneous utilization of CO₂ and CH₄ through dry reforming of methane with Ni–Ce@SiO₂ catalyst: Parametric and simulation studies

Abstract

Keywords

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