Removal of heavy metals from aqueous solution by hydroxyapatite/chitosan composite

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4 Citations (Scopus)

Abstract

Hydroxyapatite/chitosan (HApC) composite has been prepared by precipitation method and used for removal of heavy metals (Cr6+, Zn2+ and Cd2+) from aqueous solution. The HAp and 3H7C composite with HAp:chitosan ratio of 3:7 (wt%) were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy-energy dispersive X-ray spectroscopy. The SEM results showed that HAp is spherical-shaped and crystalline, while chitosan has a flat structure. SEM micrograph of 3H7C composite reveals crystalline of HAp uniformly spread over the surface of chitosan. The crystal structure of HAp is maintained in 3H7C composite. Chitosan affects the adsorption capacity of HAp for heavy metal ions; it binds the metal ions as well as HAp. The kinetic data was best described by the pseudo-second order. Surface adsorption and intraparticle diffusion take place in the mechanism of adsorption process. The binding of HAp powder with chitosan made the capability of composite to removal of Cr6+, Zn2+ and Cd2+ from aqueous solution effective. The order of removal efficiency (Cr2+ > Cd2+ > Zn2+) was observed.

Original languageEnglish
Title of host publicationAdvances in Materials, Processing and Manufacturing
Pages176-179
Number of pages4
DOIs
Publication statusPublished - 29 Oct 2013
Event13th International Conference on Quality in Research, QiR 2013 - Yogyakarta, Indonesia
Duration: 25 Jun 201328 Jun 2013

Publication series

NameAdvanced Materials Research
Volume789
ISSN (Print)1022-6680

Conference

Conference13th International Conference on Quality in Research, QiR 2013
CountryIndonesia
CityYogyakarta
Period25/06/1328/06/13

Keywords

  • Adsorption
  • Chitosan
  • Composite
  • Heavy metals
  • Hydroxyapatite

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  • Cite this

    Kusrini, E., Sofyan, N. B. I., Marta, D., Santoso, S., & Tristantini, D. (2013). Removal of heavy metals from aqueous solution by hydroxyapatite/chitosan composite. In Advances in Materials, Processing and Manufacturing (pp. 176-179). (Advanced Materials Research; Vol. 789). https://doi.org/10.4028/www.scientific.net/AMR.789.176