Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3- by mild, non-aqueous reductive aggregation

Ridla Bakri, Andrew Booth, Gavin Harle, Paul S. Middleton, Corinne Wills, William Clegg, Ross W. Harrington, R. John Errington

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Controlled reductive assembly of capped Keggin anions [PMo 12O40(MLm)n]3- has been achieved by reduction of [PMo12O40]3- with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN) 2}]3- and bi-capped [PMo12O40(VO) 2]3- and [PMo12O40Sb 2]3-.

Original languageEnglish
Pages (from-to)2779-2781
Number of pages3
JournalChemical Communications
Volume48
Issue number22
DOIs
Publication statusPublished - 14 Mar 2012

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