Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation

Ridla Bakri; Andrew Booth; Gavin Harle; Paul S. Middleton; Corinne Wills; William Clegg; Ross W. Harrington; R. John Errington

doi:10.1039/c2cc17670j

Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo₁₂O₄₀]³⁻ by mild, non-aqueous reductive aggregation

Ridla Bakri, Andrew Booth, Gavin Harle, Paul S. Middleton, Corinne Wills, William Clegg, Ross W. Harrington, R. John Errington

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Controlled reductive assembly of capped Keggin anions [PMo₁₂O₄₀(ML_m)_n]³⁻ has been achieved by reduction of [PMo₁₂O₄₀]³⁻ with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo₁₂O₄₀(Co(MeCN)₂)]³⁻ and bi-capped [PMo₁₂O₄₀(VO)₂]³⁻ and [PMo₁₂O₄₀Sb₂]³⁻.

Original language	English
Pages (from-to)	2779-2781
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	22
DOIs	https://doi.org/10.1039/c2cc17670j
Publication status	Published - 15 Feb 2012

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title = "Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation",

abstract = "Controlled reductive assembly of capped Keggin anions [PMo12O40(MLm)n]3− has been achieved by reduction of [PMo12O40]3− with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40(Co(MeCN)2)]3− and bi-capped [PMo12O40(VO)2]3− and [PMo12O40Sb2]3−.",

author = "Ridla Bakri and Andrew Booth and Gavin Harle and Middleton, {Paul S.} and Corinne Wills and William Clegg and Harrington, {Ross W.} and Errington, {R. John}",

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doi = "10.1039/c2cc17670j",

language = "English",

volume = "48",

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journal = "Chemical Communications",

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T1 - Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation

AU - Bakri, Ridla

AU - Booth, Andrew

AU - Harle, Gavin

AU - Middleton, Paul S.

AU - Wills, Corinne

AU - Clegg, William

AU - Harrington, Ross W.

AU - Errington, R. John

PY - 2012/2/15

Y1 - 2012/2/15

N2 - Controlled reductive assembly of capped Keggin anions [PMo12O40(MLm)n]3− has been achieved by reduction of [PMo12O40]3− with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40(Co(MeCN)2)]3− and bi-capped [PMo12O40(VO)2]3− and [PMo12O40Sb2]3−.

AB - Controlled reductive assembly of capped Keggin anions [PMo12O40(MLm)n]3− has been achieved by reduction of [PMo12O40]3− with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40(Co(MeCN)2)]3− and bi-capped [PMo12O40(VO)2]3− and [PMo12O40Sb2]3−.

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AN - SCOPUS:84857208007

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VL - 48

SP - 2779

EP - 2781

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo₁₂O₄₀]³⁻ by mild, non-aqueous reductive aggregation

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