PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH

Ridla Bakri

doi:10.7454/mss.v7i1.290

PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH

Ridla Bakri

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Anattempt to prepare trinuclear tungsten oxoalkoxides [BzMe3N]3[W3O8(OMe)5] from the reaction between WO2(OMe)2, [BzMe3N]2WO4 and [BzMe3N](OMe) in the ratio of 2:1:1 in MeOH produced [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH. Suitable crystals for X-ray chrystallographic studies were obtained from hot mixture of methanol-acetonitrile solution. The I.R., 1H-NMR, and microanalysis data including crystal structure of [Na2W4O12(OMe)4(MeOH)6]2- anion are reported.

Original language	English
Journal	MAKARA of Science Series
Volume	7
Issue number	1
DOIs	https://doi.org/10.7454/mss.v7i1.290
Publication status	Published - 2003

Access to Document

10.7454/mss.v7i1.290

Cite this

@article{9641c10c4cdb429687765334c803550d,

title = "PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH",

abstract = "Anattempt to prepare trinuclear tungsten oxoalkoxides [BzMe3N]3[W3O8(OMe)5] from the reaction between WO2(OMe)2, [BzMe3N]2WO4 and [BzMe3N](OMe) in the ratio of 2:1:1 in MeOH produced [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH. Suitable crystals for X-ray chrystallographic studies were obtained from hot mixture of methanol-acetonitrile solution. The I.R., 1H-NMR, and microanalysis data including crystal structure of [Na2W4O12(OMe)4(MeOH)6]2- anion are reported.",

author = "Ridla Bakri",

year = "2003",

doi = "10.7454/mss.v7i1.290",

language = "English",

volume = "7",

journal = "MAKARA of Science Series",

issn = "1693-6671",

publisher = "Universitas Indonesia",

number = "1",

}

TY - JOUR

T1 - PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH

AU - Bakri, Ridla

PY - 2003

Y1 - 2003

N2 - Anattempt to prepare trinuclear tungsten oxoalkoxides [BzMe3N]3[W3O8(OMe)5] from the reaction between WO2(OMe)2, [BzMe3N]2WO4 and [BzMe3N](OMe) in the ratio of 2:1:1 in MeOH produced [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH. Suitable crystals for X-ray chrystallographic studies were obtained from hot mixture of methanol-acetonitrile solution. The I.R., 1H-NMR, and microanalysis data including crystal structure of [Na2W4O12(OMe)4(MeOH)6]2- anion are reported.

AB - Anattempt to prepare trinuclear tungsten oxoalkoxides [BzMe3N]3[W3O8(OMe)5] from the reaction between WO2(OMe)2, [BzMe3N]2WO4 and [BzMe3N](OMe) in the ratio of 2:1:1 in MeOH produced [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH. Suitable crystals for X-ray chrystallographic studies were obtained from hot mixture of methanol-acetonitrile solution. The I.R., 1H-NMR, and microanalysis data including crystal structure of [Na2W4O12(OMe)4(MeOH)6]2- anion are reported.

UR - http://journal.ui.ac.id/index.php/science/article/view/290

U2 - 10.7454/mss.v7i1.290

DO - 10.7454/mss.v7i1.290

M3 - Article

SN - 1693-6671

VL - 7

JO - MAKARA of Science Series

JF - MAKARA of Science Series

IS - 1

ER -

PREPARATION of [BzMe3N]2[Na2W4O12(OMe)4(MeOH)6].6MeOH

Abstract

Access to Document

Other files and links

Fingerprint

Cite this