Plasmonic Temperature-Programmed Desorption

Colin J. Murphy, Hanna Härelind, Lars Hellberg, Christoph Langhammer, FERRY ANGGORO ARDY NUGROHO

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)


Temperature-programmed desorption (TPD) allows for the determination of the bonding strength and coverage of molecular mono- or multilayers on a surface and is widely used in surface science. In its traditional form using a mass spectrometric readout, this information is derived indirectly by analysis of resulting desorption peaks. This is problematic because the mass spectrometer signal not only originates from the sample surface but also potentially from other surfaces in the measurement chamber. As a complementary alternative, we introduce plasmonic TPD, which directly measures the surface coverage of molecular species adsorbed on metal nanoparticles at ultrahigh vacuum conditions. Using the examples of methanol and benzene on Au nanoparticle surfaces, the method can resolve all relevant features in the submonolayer and multilayer regimes. Furthermore, it enables the study of two types of nanoparticles simultaneously, which is challenging in a traditional TPD experiment, as we demonstrate specifically for Au and Ag.

Original languageEnglish
Pages (from-to)353-359
Number of pages7
JournalNano Letters
Issue number1
Publication statusPublished - 13 Jan 2021


  • adsorption
  • metals
  • molecules
  • nanoparticles
  • plasmonic sensing
  • temperature-programmed desorption


Dive into the research topics of 'Plasmonic Temperature-Programmed Desorption'. Together they form a unique fingerprint.

Cite this