TY - GEN
T1 - Modification of natural zeolite from Bayat with tandem acid-base treatments and cobalt (II) impregnation
AU - Ansori, Sofian
AU - Sihombing, Riwandi
AU - Krisyuningsih, Yuni
N1 - Publisher Copyright:
© 2016 Author(s).
PY - 2016/4/19
Y1 - 2016/4/19
N2 - Natural zeolite was modified using tandem acid-based treaments in order to create a mesoporous zeolite. Themesoporous zeolite was then characterized using XRD, FTIR, EDX, and AAS. The XRD patterns showed that the structure of zeolite mostly was clinoptilolite. After subjected to the tandem treatment, no significant change in the XRD patterns wasobserved. This indicates that the structure of zeolite is intact. However, the FTIR analysis shows that the wave number of functional groups in the zeolite were shifted after subjected to tandem acid-base treatment, compared to the one of the raw material. However the main functional groups of zeolites still exist after tandem acid-base treatment.The EDX analysis showed that the Si/Al ratio was increased after acid treatments (in average, approximately 1.5 times). In contrast, the Si/Al ratio was decreased from 4.50 to 4.13 after basic treatment. The mesoporous zeolite then was modified further with cobalt (II)-impregnation using incipient wetness method with variation of cobalt loading (2.5; 2.0; 1.5; 1.0; and 0.5 wt%). The Cobalt (II) mesoporous zeolite will then be used as catalyst for the production of FattyAcid Methyl Esters (FAME) from Crude Palm Oil (CPO).
AB - Natural zeolite was modified using tandem acid-based treaments in order to create a mesoporous zeolite. Themesoporous zeolite was then characterized using XRD, FTIR, EDX, and AAS. The XRD patterns showed that the structure of zeolite mostly was clinoptilolite. After subjected to the tandem treatment, no significant change in the XRD patterns wasobserved. This indicates that the structure of zeolite is intact. However, the FTIR analysis shows that the wave number of functional groups in the zeolite were shifted after subjected to tandem acid-base treatment, compared to the one of the raw material. However the main functional groups of zeolites still exist after tandem acid-base treatment.The EDX analysis showed that the Si/Al ratio was increased after acid treatments (in average, approximately 1.5 times). In contrast, the Si/Al ratio was decreased from 4.50 to 4.13 after basic treatment. The mesoporous zeolite then was modified further with cobalt (II)-impregnation using incipient wetness method with variation of cobalt loading (2.5; 2.0; 1.5; 1.0; and 0.5 wt%). The Cobalt (II) mesoporous zeolite will then be used as catalyst for the production of FattyAcid Methyl Esters (FAME) from Crude Palm Oil (CPO).
UR - http://www.scopus.com/inward/record.url?scp=84984578813&partnerID=8YFLogxK
U2 - 10.1063/1.4946948
DO - 10.1063/1.4946948
M3 - Conference contribution
AN - SCOPUS:84984578813
T3 - AIP Conference Proceedings
BT - International Symposium on Current Progress in Mathematics and Sciences 2015, ISCPMS 2015
A2 - Mart, Terry
A2 - Triyono, Djoko
PB - American Institute of Physics Inc.
T2 - 1st International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2015
Y2 - 3 November 2015 through 4 November 2015
ER -