Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method

Jessica Zivanni Wahono; Harianingsih; Miranda Talitha Z.; Nelson Saksono

doi:10.1063/5.0062197

Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method

Jessica Zivanni Wahono
, Harianingsih
, Miranda Talitha Z.
, Nelson Saksono

Department of Chemical Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

In waste, one of the important indicators is Chemical Oxygen Demand (COD). COD is the need for oxygen to oxidize organic substances contained in one liter of water. Chemical or chemical oxygen requirements for the oxidation reaction of waste materials in water. Chemical Oxygen Demand is an important water quality parameter because it can assess the effect of effluent from wastewater to be discharged into the receiving environment (water bodies). In this study, COD analysis was carried out using optimum conditions at 700 W and an air injection flow rate of 0.2 lpm, 0.02 M concentration of Na2SO4 electrolyte, 0.5 cm tungsten anode depth, 60°C of operating temperature, 100 mg/L initial phenol waste concentration, Fe2+ ion concentration 20 mg/L, volume of sample solution 1.5 L, and stirring speed 2 mot. The results showed a decrease in COD levels which only reached 71.14% due to cyclic chains in the widest area. Observation analysis of LC MS obtained the formation of intermediate compounds which include 2-Oxo-1.3-dioxole-4.5-dicarboxylic acid, ethyleneetetracarboxylic acid, and 2.2-oxydisuccinic acid.

Original language	English
Title of host publication	3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020
Editors	Is Fatimah, Won-Chun Oh, Imam Sahroni
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735441262
DOIs	https://doi.org/10.1063/5.0062197
Publication status	Published - 1 Sept 2021
Event	3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020 - Yogyakarta, Indonesia Duration: 30 Sept 2020 → …

Publication series

Name	AIP Conference Proceedings
Volume	2370
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020
Country/Territory	Indonesia
City	Yogyakarta
Period	30/09/20 → …

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 6 Clean Water and Sanitation

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10.1063/5.0062197

Cite this

Wahono, J. Z., Harianingsih, Talitha Z., M., & Saksono, N. (2021). Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method. In I. Fatimah, W.-C. Oh, & I. Sahroni (Eds.), 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020 Article 040005 (AIP Conference Proceedings; Vol. 2370). American Institute of Physics Inc.. https://doi.org/10.1063/5.0062197

Wahono, Jessica Zivanni ; Harianingsih ; Talitha Z., Miranda et al. / Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method. 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020. editor / Is Fatimah ; Won-Chun Oh ; Imam Sahroni. American Institute of Physics Inc., 2021. (AIP Conference Proceedings).

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title = "Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method",

abstract = "In waste, one of the important indicators is Chemical Oxygen Demand (COD). COD is the need for oxygen to oxidize organic substances contained in one liter of water. Chemical or chemical oxygen requirements for the oxidation reaction of waste materials in water. Chemical Oxygen Demand is an important water quality parameter because it can assess the effect of effluent from wastewater to be discharged into the receiving environment (water bodies). In this study, COD analysis was carried out using optimum conditions at 700 W and an air injection flow rate of 0.2 lpm, 0.02 M concentration of Na2SO4 electrolyte, 0.5 cm tungsten anode depth, 60°C of operating temperature, 100 mg/L initial phenol waste concentration, Fe2+ ion concentration 20 mg/L, volume of sample solution 1.5 L, and stirring speed 2 mot. The results showed a decrease in COD levels which only reached 71.14\% due to cyclic chains in the widest area. Observation analysis of LC MS obtained the formation of intermediate compounds which include 2-Oxo-1.3-dioxole-4.5-dicarboxylic acid, ethyleneetetracarboxylic acid, and 2.2-oxydisuccinic acid.",

author = "Wahono, \{Jessica Zivanni\} and Harianingsih and \{Talitha Z.\}, Miranda and Nelson Saksono",

note = "Funding Information: This research was partially funded by “ Publikasi Terindeks Internasional (PUTI) Prosiding Tahun Anggaran 2020 Contract No. NKB-1181/UN2.RST/HKP.05.00/2020” from Directorate Research and Community Service Universitas Indonesia. The authors declare no competing interests or any conflicts of financial interests. Publisher Copyright: {\textcopyright} 2021 Author(s).; 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020 ; Conference date: 30-09-2020",

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Wahono, JZ, Harianingsih, Talitha Z., M & Saksono, N 2021, Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method. in I Fatimah, W-C Oh & I Sahroni (eds), 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020., 040005, AIP Conference Proceedings, vol. 2370, American Institute of Physics Inc., 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020, Yogyakarta, Indonesia, 30/09/20. https://doi.org/10.1063/5.0062197

Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method. / Wahono, Jessica Zivanni; Harianingsih; Talitha Z., Miranda et al.
3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020. ed. / Is Fatimah; Won-Chun Oh; Imam Sahroni. American Institute of Physics Inc., 2021. 040005 (AIP Conference Proceedings; Vol. 2370).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method

AU - Wahono, Jessica Zivanni

AU - Harianingsih,

AU - Talitha Z., Miranda

AU - Saksono, Nelson

N1 - Funding Information: This research was partially funded by “ Publikasi Terindeks Internasional (PUTI) Prosiding Tahun Anggaran 2020 Contract No. NKB-1181/UN2.RST/HKP.05.00/2020” from Directorate Research and Community Service Universitas Indonesia. The authors declare no competing interests or any conflicts of financial interests. Publisher Copyright: © 2021 Author(s).

PY - 2021/9/1

Y1 - 2021/9/1

N2 - In waste, one of the important indicators is Chemical Oxygen Demand (COD). COD is the need for oxygen to oxidize organic substances contained in one liter of water. Chemical or chemical oxygen requirements for the oxidation reaction of waste materials in water. Chemical Oxygen Demand is an important water quality parameter because it can assess the effect of effluent from wastewater to be discharged into the receiving environment (water bodies). In this study, COD analysis was carried out using optimum conditions at 700 W and an air injection flow rate of 0.2 lpm, 0.02 M concentration of Na2SO4 electrolyte, 0.5 cm tungsten anode depth, 60°C of operating temperature, 100 mg/L initial phenol waste concentration, Fe2+ ion concentration 20 mg/L, volume of sample solution 1.5 L, and stirring speed 2 mot. The results showed a decrease in COD levels which only reached 71.14% due to cyclic chains in the widest area. Observation analysis of LC MS obtained the formation of intermediate compounds which include 2-Oxo-1.3-dioxole-4.5-dicarboxylic acid, ethyleneetetracarboxylic acid, and 2.2-oxydisuccinic acid.

AB - In waste, one of the important indicators is Chemical Oxygen Demand (COD). COD is the need for oxygen to oxidize organic substances contained in one liter of water. Chemical or chemical oxygen requirements for the oxidation reaction of waste materials in water. Chemical Oxygen Demand is an important water quality parameter because it can assess the effect of effluent from wastewater to be discharged into the receiving environment (water bodies). In this study, COD analysis was carried out using optimum conditions at 700 W and an air injection flow rate of 0.2 lpm, 0.02 M concentration of Na2SO4 electrolyte, 0.5 cm tungsten anode depth, 60°C of operating temperature, 100 mg/L initial phenol waste concentration, Fe2+ ion concentration 20 mg/L, volume of sample solution 1.5 L, and stirring speed 2 mot. The results showed a decrease in COD levels which only reached 71.14% due to cyclic chains in the widest area. Observation analysis of LC MS obtained the formation of intermediate compounds which include 2-Oxo-1.3-dioxole-4.5-dicarboxylic acid, ethyleneetetracarboxylic acid, and 2.2-oxydisuccinic acid.

UR - https://www.scopus.com/pages/publications/85115008970

U2 - 10.1063/5.0062197

DO - 10.1063/5.0062197

M3 - Conference contribution

AN - SCOPUS:85115008970

T3 - AIP Conference Proceedings

BT - 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020

A2 - Fatimah, Is

A2 - Oh, Won-Chun

A2 - Sahroni, Imam

PB - American Institute of Physics Inc.

T2 - 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020

Y2 - 30 September 2020

ER -

Wahono JZ, Harianingsih, Talitha Z. M, Saksono N. Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method. In Fatimah I, Oh WC, Sahroni I, editors, 3rd International Conference on Chemistry, Chemical Process and Engineering, IC3PE 2020. American Institute of Physics Inc. 2021. 040005. (AIP Conference Proceedings). doi: 10.1063/5.0062197

Liquid chromatography mass spectrometry (LC-MS) of phenol degradation using plasma electrolysis method

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