TY - JOUR
T1 - Layered 3d Transition Metal-Based Oxides for Sodium-Ion and Lithium-Ion Batteries
T2 - Differences, Links and Beyond
AU - Shi, Yuansheng
AU - Hu, Erhai
AU - Sumboja, Afriyanti
AU - Anggraningrum, Ivandini T.
AU - Syahrial, Anne Zulfia
AU - Yan, Qingyu
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024
Y1 - 2024
N2 - Due to their stable crystal framework, promising energy density, and structural versatility, layered 3d transition metal oxides have emerged as the preferred cathodes for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). While extensive research has individually addressed the lithium and sodium 3d transition metal layered oxides, the differences and interconnections between the two types of materials have largely been overlooked. Effectively utilizing these summaries is essential for driving innovative structural designs and inspiring new insights into the structure-property relationships. This review comprehensively bridges this gap by meticulously examining the disparities and links in the behavior of the layered oxides upon Li+ and Na+ storage and transfer. Key aspects, including atomic and electronic structure, phase transition mechanisms, charge compensation mechanisms and electrochemical kinetics, are carefully summarized. The implications of these aspects on the battery cycle life, energy density, and rate capability are thoroughly discussed. Additionally, by leveraging the unique characteristics of each oxide structure, this review explores the interconnection between lithium and sodium layered oxides in depth. Finally, a concise perspective on future targets and direction of 3d layered oxides is deduced and proposed.
AB - Due to their stable crystal framework, promising energy density, and structural versatility, layered 3d transition metal oxides have emerged as the preferred cathodes for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). While extensive research has individually addressed the lithium and sodium 3d transition metal layered oxides, the differences and interconnections between the two types of materials have largely been overlooked. Effectively utilizing these summaries is essential for driving innovative structural designs and inspiring new insights into the structure-property relationships. This review comprehensively bridges this gap by meticulously examining the disparities and links in the behavior of the layered oxides upon Li+ and Na+ storage and transfer. Key aspects, including atomic and electronic structure, phase transition mechanisms, charge compensation mechanisms and electrochemical kinetics, are carefully summarized. The implications of these aspects on the battery cycle life, energy density, and rate capability are thoroughly discussed. Additionally, by leveraging the unique characteristics of each oxide structure, this review explores the interconnection between lithium and sodium layered oxides in depth. Finally, a concise perspective on future targets and direction of 3d layered oxides is deduced and proposed.
KW - layered transition metal oxides
KW - Li/Na interchange
KW - lithium/sodium ion batteries
KW - metastable phases
KW - structural design
UR - http://www.scopus.com/inward/record.url?scp=85203257618&partnerID=8YFLogxK
U2 - 10.1002/adfm.202413078
DO - 10.1002/adfm.202413078
M3 - Review article
AN - SCOPUS:85203257618
SN - 1616-301X
VL - 35
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 2
M1 - 2413078
ER -