Layered 3d Transition Metal-Based Oxides for Sodium-Ion and Lithium-Ion Batteries: Differences, Links and Beyond

Yuansheng Shi, Erhai Hu, Afriyanti Sumboja, Ivandini T. Anggraningrum, Anne Zulfia Syahrial, Qingyu Yan

Research output: Contribution to journalReview articlepeer-review

Abstract

Due to their stable crystal framework, promising energy density, and structural versatility, layered 3d transition metal oxides have emerged as the preferred cathodes for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). While extensive research has individually addressed the lithium and sodium 3d transition metal layered oxides, the differences and interconnections between the two types of materials have largely been overlooked. Effectively utilizing these summaries is essential for driving innovative structural designs and inspiring new insights into the structure-property relationships. This review comprehensively bridges this gap by meticulously examining the disparities and links in the behavior of the layered oxides upon Li+ and Na+ storage and transfer. Key aspects, including atomic and electronic structure, phase transition mechanisms, charge compensation mechanisms and electrochemical kinetics, are carefully summarized. The implications of these aspects on the battery cycle life, energy density, and rate capability are thoroughly discussed. Additionally, by leveraging the unique characteristics of each oxide structure, this review explores the interconnection between lithium and sodium layered oxides in depth. Finally, a concise perspective on future targets and direction of 3d layered oxides is deduced and proposed.

Original languageEnglish
Article number2413078
JournalAdvanced Functional Materials
Volume35
Issue number2
DOIs
Publication statusAccepted/In press - 2024

Keywords

  • layered transition metal oxides
  • Li/Na interchange
  • lithium/sodium ion batteries
  • metastable phases
  • structural design

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