Intramolecular hydroamination of functionalized alkenes and alkynes with a homogenous zinc catalyst

Agustino, Maximilian Dochnahl, Dirk Hollmann, Karolin Löhnwitz, Jost Steffen Herrmann, Peter W. Roesky, Siegfried Blechert

Research output: Contribution to journalArticlepeer-review

151 Citations (Scopus)

Abstract

(Chemical Equation Presented) Simple and versatile: A new zinc complex catalyzes the intramolecular hydroamination of nonactivated alkynes and alkenes (see example in scheme; {(iPr)2ATI} = N-isopropyl-2-(isopropylamino) troponiminato). The catalyst is relatively robust, exhibits excellent activities, and tolerates various functional groups such as ethers, thioethers, and amides.

Original languageEnglish
Pages (from-to)7794-7798
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number47
DOIs
Publication statusPublished - 2 Dec 2005

Keywords

  • Cyclization
  • Heterocycles
  • Homogenous catalysis
  • Hydroamination
  • Zinc

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