FACILE SYNTHESIS OF Ni-AND NiCo-MODIFIED MESOPOROUS CARBON AND ITS CATALYTIC ACTIVITY FOR PHENYLACETYLENE REDUCTION TO STYRENE UNDER AN ATMOSPHERIC HYDROGEN

I. Abdullah; T. M. Ratu; M. Ridwan; Y. K. Krisnandi

doi:10.31788/RJC.2022.1536714

FACILE SYNTHESIS OF Ni-AND NiCo-MODIFIED MESOPOROUS CARBON AND ITS CATALYTIC ACTIVITY FOR PHENYLACETYLENE REDUCTION TO STYRENE UNDER AN ATMOSPHERIC HYDROGEN

I. Abdullah, T. M. Ratu, M. Ridwan, Y. K. Krisnandi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Mesoporous carbon (MC) has been successfully synthesized via the soft template method and further impregnated with monometallic Ni and bimetallic Ni-Co to give Ni-modified MC (Ni/MC) and NiCo/MC, respectively. The modified MC materials were characterized using XRD, SEM-EDX, SAA, and TEM. The results of the TEM analysis showed that the metal was homogeneously distributed on MC with the average particle sizes of Ni and bimetallic NiCo being 23.1 and 10.4 nm, respectively. The results of BET analysis show that the materials have a high surface area of 304, 289, and 313 m²/g for MC, Ni/MC, and NiCo/MC, respectively. Both Ni/MC and bimetallic NiCo/MC were then used as catalysts in phenylacetylene hydrogenation under atmospheric hydrogen pressure.

Original language	English
Pages (from-to)	1882-1887
Number of pages	6
Journal	Rasayan Journal of Chemistry
Volume	15
Issue number	3
DOIs	https://doi.org/10.31788/RJC.2022.1536714
Publication status	Published - 1 Jul 2022

Keywords

Bimetallic NiCo
Hydrogenation Reaction
Mesoporous Carbon
Nickel
Phenylacetylene

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10.31788/RJC.2022.1536714

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title = "FACILE SYNTHESIS OF Ni-AND NiCo-MODIFIED MESOPOROUS CARBON AND ITS CATALYTIC ACTIVITY FOR PHENYLACETYLENE REDUCTION TO STYRENE UNDER AN ATMOSPHERIC HYDROGEN",

abstract = "Mesoporous carbon (MC) has been successfully synthesized via the soft template method and further impregnated with monometallic Ni and bimetallic Ni-Co to give Ni-modified MC (Ni/MC) and NiCo/MC, respectively. The modified MC materials were characterized using XRD, SEM-EDX, SAA, and TEM. The results of the TEM analysis showed that the metal was homogeneously distributed on MC with the average particle sizes of Ni and bimetallic NiCo being 23.1 and 10.4 nm, respectively. The results of BET analysis show that the materials have a high surface area of 304, 289, and 313 m2/g for MC, Ni/MC, and NiCo/MC, respectively. Both Ni/MC and bimetallic NiCo/MC were then used as catalysts in phenylacetylene hydrogenation under atmospheric hydrogen pressure.",

keywords = "Bimetallic NiCo, Hydrogenation Reaction, Mesoporous Carbon, Nickel, Phenylacetylene",

author = "I. Abdullah and Ratu, {T. M.} and M. Ridwan and Krisnandi, {Y. K.}",

note = "Funding Information: This work was supported by the Directorate of Research and Development, Universitas Indonesia under PUTI Research Grant contract no. NKB-1974/UN2.RST/HKP.05.00/2020. Publisher Copyright: {\textcopyright} 2022, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.",

year = "2022",

month = jul,

day = "1",

doi = "10.31788/RJC.2022.1536714",

language = "English",

volume = "15",

pages = "1882--1887",

journal = "Rasayan Journal of Chemistry",

issn = "0974-1496",

publisher = "Rasayan Journal",

number = "3",

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T1 - FACILE SYNTHESIS OF Ni-AND NiCo-MODIFIED MESOPOROUS CARBON AND ITS CATALYTIC ACTIVITY FOR PHENYLACETYLENE REDUCTION TO STYRENE UNDER AN ATMOSPHERIC HYDROGEN

AU - Abdullah, I.

AU - Ratu, T. M.

AU - Ridwan, M.

AU - Krisnandi, Y. K.

N1 - Funding Information: This work was supported by the Directorate of Research and Development, Universitas Indonesia under PUTI Research Grant contract no. NKB-1974/UN2.RST/HKP.05.00/2020. Publisher Copyright: © 2022, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.

PY - 2022/7/1

Y1 - 2022/7/1

N2 - Mesoporous carbon (MC) has been successfully synthesized via the soft template method and further impregnated with monometallic Ni and bimetallic Ni-Co to give Ni-modified MC (Ni/MC) and NiCo/MC, respectively. The modified MC materials were characterized using XRD, SEM-EDX, SAA, and TEM. The results of the TEM analysis showed that the metal was homogeneously distributed on MC with the average particle sizes of Ni and bimetallic NiCo being 23.1 and 10.4 nm, respectively. The results of BET analysis show that the materials have a high surface area of 304, 289, and 313 m2/g for MC, Ni/MC, and NiCo/MC, respectively. Both Ni/MC and bimetallic NiCo/MC were then used as catalysts in phenylacetylene hydrogenation under atmospheric hydrogen pressure.

AB - Mesoporous carbon (MC) has been successfully synthesized via the soft template method and further impregnated with monometallic Ni and bimetallic Ni-Co to give Ni-modified MC (Ni/MC) and NiCo/MC, respectively. The modified MC materials were characterized using XRD, SEM-EDX, SAA, and TEM. The results of the TEM analysis showed that the metal was homogeneously distributed on MC with the average particle sizes of Ni and bimetallic NiCo being 23.1 and 10.4 nm, respectively. The results of BET analysis show that the materials have a high surface area of 304, 289, and 313 m2/g for MC, Ni/MC, and NiCo/MC, respectively. Both Ni/MC and bimetallic NiCo/MC were then used as catalysts in phenylacetylene hydrogenation under atmospheric hydrogen pressure.

KW - Bimetallic NiCo

KW - Hydrogenation Reaction

KW - Mesoporous Carbon

KW - Nickel

KW - Phenylacetylene

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DO - 10.31788/RJC.2022.1536714

M3 - Article

AN - SCOPUS:85136217905

SN - 0974-1496

VL - 15

SP - 1882

EP - 1887

JO - Rasayan Journal of Chemistry

JF - Rasayan Journal of Chemistry

IS - 3

ER -

FACILE SYNTHESIS OF Ni-AND NiCo-MODIFIED MESOPOROUS CARBON AND ITS CATALYTIC ACTIVITY FOR PHENYLACETYLENE REDUCTION TO STYRENE UNDER AN ATMOSPHERIC HYDROGEN

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Keywords

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