TY - JOUR
T1 - Evaluation of the interaction between molecules during betaine monohydrate-organic acid deep eutectic mixture formation
AU - Zahrina, Ida
AU - Nasikin, Mohammad
AU - Mulia, Kamarza
N1 - Funding Information:
The authors wish to acknowledge Indonesian Agency for Agricultural Research and Development (IAARD) research grant number 138/PL.220/I.1/3/2014.k for the financial support.
Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Deep eutectic solvents (DES) are attractive as green media because DES are non-toxic and biodegradable. DES are obtained by mixing a quaternary ammonium salt with a hydrogen bond donor (HBD) until they form a eutectic mixture. Recently, DES have been widely applied as solvents for extraction processes. Because the solutes and HBD competitively interact with salt during the extraction process, the stability and strength of the interaction between salt and HBD molecules on DES formation should be evaluated. In this study, the interactions between molecules of the betaine monohydrate salt and different HBDs consisting of liquid organic acids (i.e., propionic and acetic acid) in eutectic mixture formation were investigated by thermodynamic and spectroscopic analyses. On the basis of thermodynamic analysis, the stability and strength of the molecular interaction between betaine monohydrate and propionic acid was greater than the stability and strength of the molecular interaction between betaine monohydrate and acetic acid. The total interaction energy between the betaine monohydrate and propionic acid molecules was − 15.7 kJ·mol− 1, with an excess Gibbs free energy (GE) of 0.81 kJ·mol− 1 at the eutectic composition. The spectroscopic analysis indicates the presence of a weak interaction between the betaine monohydrate and acid molecules.
AB - Deep eutectic solvents (DES) are attractive as green media because DES are non-toxic and biodegradable. DES are obtained by mixing a quaternary ammonium salt with a hydrogen bond donor (HBD) until they form a eutectic mixture. Recently, DES have been widely applied as solvents for extraction processes. Because the solutes and HBD competitively interact with salt during the extraction process, the stability and strength of the interaction between salt and HBD molecules on DES formation should be evaluated. In this study, the interactions between molecules of the betaine monohydrate salt and different HBDs consisting of liquid organic acids (i.e., propionic and acetic acid) in eutectic mixture formation were investigated by thermodynamic and spectroscopic analyses. On the basis of thermodynamic analysis, the stability and strength of the molecular interaction between betaine monohydrate and propionic acid was greater than the stability and strength of the molecular interaction between betaine monohydrate and acetic acid. The total interaction energy between the betaine monohydrate and propionic acid molecules was − 15.7 kJ·mol− 1, with an excess Gibbs free energy (GE) of 0.81 kJ·mol− 1 at the eutectic composition. The spectroscopic analysis indicates the presence of a weak interaction between the betaine monohydrate and acid molecules.
KW - Betaine monohydrate
KW - DES
KW - Molecular interaction
KW - Organic acid
KW - Stability and strength
UR - http://www.scopus.com/inward/record.url?scp=85002158031&partnerID=8YFLogxK
U2 - 10.1016/j.molliq.2016.10.134
DO - 10.1016/j.molliq.2016.10.134
M3 - Article
AN - SCOPUS:85002158031
SN - 0167-7322
VL - 225
SP - 446
EP - 450
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
ER -