Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel

M. I. Andra; D. U.C. Rahayu; I. Abdullah; Y. Krisnandi

doi:10.1063/5.0008002

Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel

M. I. Andra, D. U.C. Rahayu, I. Abdullah, Y. Krisnandi

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Citations (Scopus)

Abstract

Imidazoline is an organic compound that widely used as a corrosion inhibitor. Based on its structure, imidazoline is a heterocyclic compound having a pendant group and hydrocarbon chain which important for its activity as corrosion inhibitor. This research was conducted to modify the imidazoline structure to increase its activity in inhibiting corrosion towards carbon steel. In this research, ester-imidazoline from aminoethylethanolamine (AEEA) and oleic acid (OA) was successfully synthesized with an equivalent ratio of 1:2 (mole/mole) in xylene solvent with various reaction times using MAOS (Microwave Assisted Organic Synthesis) method. The optimum yield was obtained at 9 min reached 87.53 % yield. Ester-imidazoline was analyzed using thin layer chromatography (TLC) and elucidated using FTIR, UV-Vis, and ¹H-NMR spectral data. Furthermore, the ability of ester-imidazoline to inhibit corrosion was measured towards carbon steel in 1% NaCl with various concentrations using Tafel polarization method to afford the inhibition efficiency (% IE). The highest % IE was yielded in 100 ppm with % IE value of 51.26 %. This study reported the first modification of imidazoline to yield ester-imidazoline using MAOS method along with its anticorrosion activity.

Original language	English
Title of host publication	Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019
Editors	Terry Mart, Djoko Triyono, Tribidasari Anggraningrum Ivandini
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735420014
DOIs	https://doi.org/10.1063/5.0008002
Publication status	Published - 1 Jun 2020
Event	5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019 - Depok, Indonesia Duration: 9 Jul 2019 → 10 Jul 2019

Publication series

Name	AIP Conference Proceedings
Volume	2242
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019
Country/Territory	Indonesia
City	Depok
Period	9/07/19 → 10/07/19

Keywords

Aminoethylethanolamine
corrosion inhibitor
ester-imidazoline
imidazoline
MAOS

Access to Document

10.1063/5.0008002

Cite this

Andra, M. I., Rahayu, D. U. C., Abdullah, I., & Krisnandi, Y. (2020). Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel. In T. Mart, D. Triyono, & T. A. Ivandini (Eds.), Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019 [040018] (AIP Conference Proceedings; Vol. 2242). American Institute of Physics Inc.. https://doi.org/10.1063/5.0008002

Andra, M. I. ; Rahayu, D. U.C. ; Abdullah, I. et al. / Ester-imidazoline : Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel. Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019. editor / Terry Mart ; Djoko Triyono ; Tribidasari Anggraningrum Ivandini. American Institute of Physics Inc., 2020. (AIP Conference Proceedings).

@inproceedings{12083cfcadb04e78937697b9aa8c4ca8,

title = "Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel",

abstract = "Imidazoline is an organic compound that widely used as a corrosion inhibitor. Based on its structure, imidazoline is a heterocyclic compound having a pendant group and hydrocarbon chain which important for its activity as corrosion inhibitor. This research was conducted to modify the imidazoline structure to increase its activity in inhibiting corrosion towards carbon steel. In this research, ester-imidazoline from aminoethylethanolamine (AEEA) and oleic acid (OA) was successfully synthesized with an equivalent ratio of 1:2 (mole/mole) in xylene solvent with various reaction times using MAOS (Microwave Assisted Organic Synthesis) method. The optimum yield was obtained at 9 min reached 87.53 % yield. Ester-imidazoline was analyzed using thin layer chromatography (TLC) and elucidated using FTIR, UV-Vis, and 1H-NMR spectral data. Furthermore, the ability of ester-imidazoline to inhibit corrosion was measured towards carbon steel in 1% NaCl with various concentrations using Tafel polarization method to afford the inhibition efficiency (% IE). The highest % IE was yielded in 100 ppm with % IE value of 51.26 %. This study reported the first modification of imidazoline to yield ester-imidazoline using MAOS method along with its anticorrosion activity.",

keywords = "Aminoethylethanolamine, corrosion inhibitor, ester-imidazoline, imidazoline, MAOS",

author = "Andra, {M. I.} and Rahayu, {D. U.C.} and I. Abdullah and Y. Krisnandi",

note = "Funding Information: This work was supported by PIT9 2019 research grant No. NKB-0038/UN2.R3.1/HKP.05.00/2019 from DRPM Universitas Indonesia. Publisher Copyright: {\textcopyright} 2020 Author(s).; 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019 ; Conference date: 09-07-2019 Through 10-07-2019",

year = "2020",

month = jun,

day = "1",

doi = "10.1063/5.0008002",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

editor = "Terry Mart and Djoko Triyono and Ivandini, {Tribidasari Anggraningrum}",

booktitle = "Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019",

}

Andra, MI, Rahayu, DUC , Abdullah, I & Krisnandi, Y 2020, Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel. in T Mart, D Triyono & TA Ivandini (eds), Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019., 040018, AIP Conference Proceedings, vol. 2242, American Institute of Physics Inc., 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019, Depok, Indonesia, 9/07/19. https://doi.org/10.1063/5.0008002

Ester-imidazoline : Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel. / Andra, M. I.; Rahayu, D. U.C.; Abdullah, I. et al.

Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019. ed. / Terry Mart; Djoko Triyono; Tribidasari Anggraningrum Ivandini. American Institute of Physics Inc., 2020. 040018 (AIP Conference Proceedings; Vol. 2242).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Ester-imidazoline

T2 - 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019

AU - Andra, M. I.

AU - Rahayu, D. U.C.

AU - Abdullah, I.

AU - Krisnandi, Y.

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Imidazoline is an organic compound that widely used as a corrosion inhibitor. Based on its structure, imidazoline is a heterocyclic compound having a pendant group and hydrocarbon chain which important for its activity as corrosion inhibitor. This research was conducted to modify the imidazoline structure to increase its activity in inhibiting corrosion towards carbon steel. In this research, ester-imidazoline from aminoethylethanolamine (AEEA) and oleic acid (OA) was successfully synthesized with an equivalent ratio of 1:2 (mole/mole) in xylene solvent with various reaction times using MAOS (Microwave Assisted Organic Synthesis) method. The optimum yield was obtained at 9 min reached 87.53 % yield. Ester-imidazoline was analyzed using thin layer chromatography (TLC) and elucidated using FTIR, UV-Vis, and 1H-NMR spectral data. Furthermore, the ability of ester-imidazoline to inhibit corrosion was measured towards carbon steel in 1% NaCl with various concentrations using Tafel polarization method to afford the inhibition efficiency (% IE). The highest % IE was yielded in 100 ppm with % IE value of 51.26 %. This study reported the first modification of imidazoline to yield ester-imidazoline using MAOS method along with its anticorrosion activity.

AB - Imidazoline is an organic compound that widely used as a corrosion inhibitor. Based on its structure, imidazoline is a heterocyclic compound having a pendant group and hydrocarbon chain which important for its activity as corrosion inhibitor. This research was conducted to modify the imidazoline structure to increase its activity in inhibiting corrosion towards carbon steel. In this research, ester-imidazoline from aminoethylethanolamine (AEEA) and oleic acid (OA) was successfully synthesized with an equivalent ratio of 1:2 (mole/mole) in xylene solvent with various reaction times using MAOS (Microwave Assisted Organic Synthesis) method. The optimum yield was obtained at 9 min reached 87.53 % yield. Ester-imidazoline was analyzed using thin layer chromatography (TLC) and elucidated using FTIR, UV-Vis, and 1H-NMR spectral data. Furthermore, the ability of ester-imidazoline to inhibit corrosion was measured towards carbon steel in 1% NaCl with various concentrations using Tafel polarization method to afford the inhibition efficiency (% IE). The highest % IE was yielded in 100 ppm with % IE value of 51.26 %. This study reported the first modification of imidazoline to yield ester-imidazoline using MAOS method along with its anticorrosion activity.

KW - Aminoethylethanolamine

KW - corrosion inhibitor

KW - ester-imidazoline

KW - imidazoline

KW - MAOS

UR - http://www.scopus.com/inward/record.url?scp=85086653241&partnerID=8YFLogxK

U2 - 10.1063/5.0008002

DO - 10.1063/5.0008002

M3 - Conference contribution

AN - SCOPUS:85086653241

T3 - AIP Conference Proceedings

BT - Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019

A2 - Mart, Terry

A2 - Triyono, Djoko

A2 - Ivandini, Tribidasari Anggraningrum

PB - American Institute of Physics Inc.

Y2 - 9 July 2019 through 10 July 2019

ER -

Andra MI, Rahayu DUC , Abdullah I , Krisnandi Y. Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel. In Mart T, Triyono D, Ivandini TA, editors, Proceedings of the 5th International Symposium on Current Progress in Mathematics and Sciences, ISCPMS 2019. American Institute of Physics Inc. 2020. 040018. (AIP Conference Proceedings). doi: 10.1063/5.0008002

Ester-imidazoline: Modification of imidazoline using MAOS (microwave assisted organic synthesis) method as corrosion inhibitor towards carbon steel

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