@article{87446240528848978da1fdecb8a3c6d7,
title = "Enantioselective synthesis of β-amino acid derivatives: Via nickel-promoted regioselective carboxylation of ynamides and rhodium-catalyzed asymmetric hydrogenation",
abstract = "We succeeded in the development of a new method for enantioselective synthesis of α-substituted-β-amino acid derivatives. Thus, nickel(0)-promoted carboxylation of ynamide gave the α-substituted-β-aminoacrylate derivative in a highly regioselective manner. Then, rhodium-catalyzed asymmetric hydrogenation of the α-substituted β-aminoacrylate produced the corresponding α-substituted β-amino acid derivative as an optically active form.",
author = "Nozomi Saito and Iman Abdullah and Kayoko Hayashi and Katsuyuki Hamada and Momoko Koyama and Yoshihiro Sato",
note = "Funding Information: This work was supported by the research area of JST Creation of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load (ACT-C), by a Grant-in-Aid for Scientific Research (C) (No. 26460002) and a Grant-in-Aid for Scientific Research (B) (No. 26293001) from JSPS and by a Grant-in-Aid for Scientific Research on Innovative Areas Molecular Activation Directed toward Straightforward Synthesis (No. 23105501 and 25105701). N. S. acknowledges Takeda Science Foundation for financial support. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",
year = "2016",
doi = "10.1039/c6ob01234e",
language = "English",
volume = "14",
pages = "10080--10089",
journal = "Organic and Biomolecular Chemistry",
issn = "1477-0520",
publisher = "Royal Society of Chemistry",
number = "42",
}