Electrosynthesis of vanillin from isoeugenol using platinum electrode

H. Mubarok; Hilyatudini; Endang Saefudin; Ivandini Tribidasari Anggraningrum

doi:10.1088/1757-899X/188/1/012050

Electrosynthesis of vanillin from isoeugenol using platinum electrode

H. Mubarok, Hilyatudini, Endang Saefudin, Ivandini Tribidasari Anggraningrum

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

4 Citations (Scopus)

Abstract

Vanillin was synthesized from isoeugenol through electrochemical method in one compartment cell using platinum electrode. Cyclic voltammetry in 0.1 M TBAP in methanol and acetonitrile indicated the first oxidation potential at +0.21 and +0.16 V (vs. Ag/AgCl), respectively. Isoeugenolis was proposed to undergo the oxidation accompanied by oxidative cleavage of alkene bond into aldehyde. Accordingly, the synthesis of vanillin was conducted using chronoamperometry technique. The electrosynthesis result was analyzed by HPLC and GC/MS. The optimum condition of the oxidation potential, solvent ratio, time of electrolysis and amount of water was investigated.

Original language	English
Article number	012050
Journal	IOP Conference Series: Materials Science and Engineering
Volume	188
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/188/1/012050
Publication status	Published - 2 May 2017
Event	International Symposium on Current Progress in Functional Materials 2016, ISCPFM 2016 - Bali, Indonesia Duration: 26 Jul 2016 → 27 Jul 2016

Keywords

electrosynthesis
isoeugenol
oxidative cleavage
vanillin

Access to Document

10.1088/1757-899X/188/1/012050

Cite this

@article{90c7db4bd6094527bbcfa2385912c9f3,

title = "Electrosynthesis of vanillin from isoeugenol using platinum electrode",

abstract = "Vanillin was synthesized from isoeugenol through electrochemical method in one compartment cell using platinum electrode. Cyclic voltammetry in 0.1 M TBAP in methanol and acetonitrile indicated the first oxidation potential at +0.21 and +0.16 V (vs. Ag/AgCl), respectively. Isoeugenolis was proposed to undergo the oxidation accompanied by oxidative cleavage of alkene bond into aldehyde. Accordingly, the synthesis of vanillin was conducted using chronoamperometry technique. The electrosynthesis result was analyzed by HPLC and GC/MS. The optimum condition of the oxidation potential, solvent ratio, time of electrolysis and amount of water was investigated.",

keywords = "electrosynthesis, isoeugenol, oxidative cleavage, vanillin",

author = "H. Mubarok and Hilyatudini and Endang Saefudin and Anggraningrum, {Ivandini Tribidasari}",

note = "Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd.; International Symposium on Current Progress in Functional Materials 2016, ISCPFM 2016 ; Conference date: 26-07-2016 Through 27-07-2016",

year = "2017",

month = may,

day = "2",

doi = "10.1088/1757-899X/188/1/012050",

language = "English",

volume = "188",

journal = "IOP Conference Series: Materials Science and Engineering",

issn = "1757-8981",

publisher = "IOP Publishing Ltd.",

number = "1",

}

TY - JOUR

T1 - Electrosynthesis of vanillin from isoeugenol using platinum electrode

AU - Mubarok, H.

AU - Hilyatudini,

AU - Saefudin, Endang

AU - Anggraningrum, Ivandini Tribidasari

N1 - Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2017/5/2

Y1 - 2017/5/2

N2 - Vanillin was synthesized from isoeugenol through electrochemical method in one compartment cell using platinum electrode. Cyclic voltammetry in 0.1 M TBAP in methanol and acetonitrile indicated the first oxidation potential at +0.21 and +0.16 V (vs. Ag/AgCl), respectively. Isoeugenolis was proposed to undergo the oxidation accompanied by oxidative cleavage of alkene bond into aldehyde. Accordingly, the synthesis of vanillin was conducted using chronoamperometry technique. The electrosynthesis result was analyzed by HPLC and GC/MS. The optimum condition of the oxidation potential, solvent ratio, time of electrolysis and amount of water was investigated.

AB - Vanillin was synthesized from isoeugenol through electrochemical method in one compartment cell using platinum electrode. Cyclic voltammetry in 0.1 M TBAP in methanol and acetonitrile indicated the first oxidation potential at +0.21 and +0.16 V (vs. Ag/AgCl), respectively. Isoeugenolis was proposed to undergo the oxidation accompanied by oxidative cleavage of alkene bond into aldehyde. Accordingly, the synthesis of vanillin was conducted using chronoamperometry technique. The electrosynthesis result was analyzed by HPLC and GC/MS. The optimum condition of the oxidation potential, solvent ratio, time of electrolysis and amount of water was investigated.

KW - electrosynthesis

KW - isoeugenol

KW - oxidative cleavage

KW - vanillin

UR - http://www.scopus.com/inward/record.url?scp=85019736007&partnerID=8YFLogxK

U2 - 10.1088/1757-899X/188/1/012050

DO - 10.1088/1757-899X/188/1/012050

M3 - Conference article

AN - SCOPUS:85019736007

SN - 1757-8981

VL - 188

JO - IOP Conference Series: Materials Science and Engineering

JF - IOP Conference Series: Materials Science and Engineering

IS - 1

M1 - 012050

T2 - International Symposium on Current Progress in Functional Materials 2016, ISCPFM 2016

Y2 - 26 July 2016 through 27 July 2016

ER -

Electrosynthesis of vanillin from isoeugenol using platinum electrode

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this