Electrical properties of La0.7Ba0.297Ca0.003MnO3 obtained by low temperature sol-gel synthesis

S. Winarsih, B. Kurniawan, A. Imaduddin, A. Manaf

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Citations (Scopus)

Abstract

A compound of La0.7Ba0.297Ca0.003MnO3 was obtained by low temperature sol-gel synthesis. The structural and electrical properties of the material were systematically studied. La0.7Ba0.297Ca0.003MnO3 material is a member of mixed valence manganites which has a perovskite structure. The general structure is AMnO3 (A= trivalent rare earth with divalent ion-doped such as Sr2+, Ca2+, Ba2+, etc). The previous study proved that doped Ca2+ ion to the La0.7Ba0.3MnO3 material increased its CMR effect and MCE effect and decreased its Tc become near room temperature. CMR effect is change of resistivity due to external magnetic field in the perovskite-based material. Meanwhile, MCE (Magnetocaloric effect) is thermal response from material due to external magnetic field. In this work, we focus only on the electrical properties of La0.7Ba0.297Ca0.003MnO3 (low doped calcium content in the La0.7Ba0.3MnO3 material) obtained by low temperature sol-gel synthesis. The X-ray diffraction pattern shows that the material is fully crystalline with a rhombohedral structure and R-3c space group. Polycrystalline La0.7Ba0.297Ca0.003MnO3 has magnetic transition behavior from metallic-ferromagnetic behavior to the insulator-paramagnetic behavior with increasing temperature. This material also has magnetoresistance effect. Magnetoresistance value of the material is about 9% at 280 K under an external magnetic field of 1.5 T. In this case, extrinsic MR (extrinsic magnetoresistance) plays an important role since the material is polycrystalline. From this study, we conclude that with low temperature processing we obtained material that has CMR effect and magnetic transition phenomenon like material which prepared by high temperature processing.

Original languageEnglish
Title of host publicationInternational Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016
Subtitle of host publicationProceedings of the 2nd International Symposium on Current Progress in Mathematics and Sciences 2016
EditorsKiki Ariyanti Sugeng, Djoko Triyono, Terry Mart
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735415362
DOIs
Publication statusPublished - 10 Jul 2017
Event2nd International Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016 - Depok, Jawa Barat, Indonesia
Duration: 1 Nov 20162 Nov 2016

Publication series

NameAIP Conference Proceedings
Volume1862
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference2nd International Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016
Country/TerritoryIndonesia
CityDepok, Jawa Barat
Period1/11/162/11/16

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