Effects of ion exchange on the structure of ETS-10

Yuni Krisyuningsih; Eric E. Lachowski; Russell F. Howe

doi:10.1021/cm051785g

Effects of ion exchange on the structure of ETS-10

Yuni Krisyuningsih, Eric E. Lachowski, Russell F. Howe

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A detailed characterization study is reported of ETS-10 subjected to ammonium ion exchange and subsequent sodium ion back exchange. It is shown that although such ion exchange leaves the crystallinity of ETS-10 measured by X-ray powder diffraction unchanged, other techniques reveal that the structure becomes locally damaged. In particular, there is partial dissolution of silica from the outer regions of ETS-10 crystallites under low pH conditions, exposing titania-rich surface sites and substantially modifying the photoreactivity of the material.

Original language	English
Pages (from-to)	928-933
Number of pages	6
Journal	Chemistry of Materials
Volume	18
Issue number	4
DOIs	https://doi.org/10.1021/cm051785g
Publication status	Published - 21 Feb 2006

Access to Document

10.1021/cm051785g

Cite this

@article{c05dcc1cc8554de281db2b3549660f69,

title = "Effects of ion exchange on the structure of ETS-10",

abstract = "A detailed characterization study is reported of ETS-10 subjected to ammonium ion exchange and subsequent sodium ion back exchange. It is shown that although such ion exchange leaves the crystallinity of ETS-10 measured by X-ray powder diffraction unchanged, other techniques reveal that the structure becomes locally damaged. In particular, there is partial dissolution of silica from the outer regions of ETS-10 crystallites under low pH conditions, exposing titania-rich surface sites and substantially modifying the photoreactivity of the material.",

author = "Yuni Krisyuningsih and Lachowski, {Eric E.} and Howe, {Russell F.}",

year = "2006",

month = feb,

day = "21",

doi = "10.1021/cm051785g",

language = "English",

volume = "18",

pages = "928--933",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Effects of ion exchange on the structure of ETS-10

AU - Krisyuningsih, Yuni

AU - Lachowski, Eric E.

AU - Howe, Russell F.

PY - 2006/2/21

Y1 - 2006/2/21

N2 - A detailed characterization study is reported of ETS-10 subjected to ammonium ion exchange and subsequent sodium ion back exchange. It is shown that although such ion exchange leaves the crystallinity of ETS-10 measured by X-ray powder diffraction unchanged, other techniques reveal that the structure becomes locally damaged. In particular, there is partial dissolution of silica from the outer regions of ETS-10 crystallites under low pH conditions, exposing titania-rich surface sites and substantially modifying the photoreactivity of the material.

AB - A detailed characterization study is reported of ETS-10 subjected to ammonium ion exchange and subsequent sodium ion back exchange. It is shown that although such ion exchange leaves the crystallinity of ETS-10 measured by X-ray powder diffraction unchanged, other techniques reveal that the structure becomes locally damaged. In particular, there is partial dissolution of silica from the outer regions of ETS-10 crystallites under low pH conditions, exposing titania-rich surface sites and substantially modifying the photoreactivity of the material.

UR - http://www.scopus.com/inward/record.url?scp=33644617344&partnerID=8YFLogxK

U2 - 10.1021/cm051785g

DO - 10.1021/cm051785g

M3 - Article

AN - SCOPUS:33644617344

SN - 0897-4756

VL - 18

SP - 928

EP - 933

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 4

ER -

Effects of ion exchange on the structure of ETS-10

Abstract

Access to Document

Other files and links

Fingerprint

Cite this