Effect of secondary template polarity to the properties of mesoporous ZSM-5 zeolites

T. M. Karim, R. Nuzuliyah, D. A. Nurani, Y. K. Krisnandi

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Citations (Scopus)

Abstract

Synthesis and characterization of mesoporous ZSM-5 using two kinds of secondary templates with different polarity, polydiallyldimethylammonium chloride (PDDA-Cl) or cetyltrimethylammonium bromide (CTABr) were studied. The weight lost after calcination at 550 °C for 5 hours were 30.93 wt% and 25.87 wt% for PDDA-Cl-templated ZSM-5 (ZSM-5pc) and CTABr-templated ZSM-5 (ZSM-5cs), respectively. Both as-synthesized mesoporous ZSM-5 zeolites then were characterized by XRD, FTIR, SEM, and EDX. Based on wide angle XRD analysis that both mesoporous ZSM-5 showed similar diffraction patterns and the typical peaks of ZSM-5 in which 2θ = 7°-9° (doublet peaks) and 22°-25° (triplet peaks) appeared. For the analysis of functional group, FTIR analysis showed that both mesoporous ZSM-5 gave strong band at 550 cm-1, which is attributed to asymmetric stretching vibration of the double 5-rings from MFI zeolites. Meanwhile, the result of EDX calculation showed mesoporous ZSM-5pc had Si/Al ratio of and ZSM-5cs had Si/Al ratio of 12.62. Furthermore, the SEM images exhibited mesoporous ZSM-5pc had morphology of hexagonal (coffin-like) while ZSM-5cs had ellipse form.

Original languageEnglish
Title of host publicationInternational Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016
Subtitle of host publicationProceedings of the 2nd International Symposium on Current Progress in Mathematics and Sciences 2016
EditorsKiki Ariyanti Sugeng, Djoko Triyono, Terry Mart
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735415362
DOIs
Publication statusPublished - 10 Jul 2017
Event2nd International Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016 - Depok, Jawa Barat, Indonesia
Duration: 1 Nov 20162 Nov 2016

Publication series

NameAIP Conference Proceedings
Volume1862
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference2nd International Symposium on Current Progress in Mathematics and Sciences 2016, ISCPMS 2016
Country/TerritoryIndonesia
CityDepok, Jawa Barat
Period1/11/162/11/16

Keywords

  • Si/Al ratio
  • functional group
  • mesoporous ZSM-5
  • morphology
  • secondary template

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