TY - JOUR
T1 - Crystallite structure of Palm shell Activated Carbon/MgO and Its Influence on Carbon Monoxide and Carbon Dioxide Adsorption
AU - Yuliusman,
AU - Nafisah, A. R.
N1 - Funding Information:
This work is financially supported by the Directorate General of Higher Education, Ministry of Education and Culture, Republic of Indonesia through the master's grant. Authors also thankful for all the support from colleagues.
Publisher Copyright:
© Published under licence by IOP Publishing Ltd.
PY - 2021/6/7
Y1 - 2021/6/7
N2 - Gas emission of the motor vehicle is a major contributor to climate change, with a total of 14% emission annually, and the best potential option for reducing pollution is using the adsorption method. Magnesium oxide (MgO) has been proven as an effective adsorbent for liquid and gases. The impregnation of MgO on porous structure increases the affinity toward nonpolar gases, which is one of the purposes of this study. The crystallite structure is also a key factor that determines the adsorption capacity of activated carbon (AC). However, deeper analysis is needed in the activated carbon crystallite structure represented by d002 (aromatic layer), Lc (crystallite height), and La (crystallite diameter) on the adsorption of motor vehicle gas emissions. Three types of palm shell-based activated carbon were tested in this experiment. The results showed that activated carbon made using the two-step method and the AC/MgO produced surface structure with a d002 value of 0.33 nm and 0.32 nm, respectively. The impregnation of MgO on AC showed changes in surface structure and affected its crystallinity. The ability to adsorb CO2 and CO by AC/MgO increase up to 80% and 88%, respectively.
AB - Gas emission of the motor vehicle is a major contributor to climate change, with a total of 14% emission annually, and the best potential option for reducing pollution is using the adsorption method. Magnesium oxide (MgO) has been proven as an effective adsorbent for liquid and gases. The impregnation of MgO on porous structure increases the affinity toward nonpolar gases, which is one of the purposes of this study. The crystallite structure is also a key factor that determines the adsorption capacity of activated carbon (AC). However, deeper analysis is needed in the activated carbon crystallite structure represented by d002 (aromatic layer), Lc (crystallite height), and La (crystallite diameter) on the adsorption of motor vehicle gas emissions. Three types of palm shell-based activated carbon were tested in this experiment. The results showed that activated carbon made using the two-step method and the AC/MgO produced surface structure with a d002 value of 0.33 nm and 0.32 nm, respectively. The impregnation of MgO on AC showed changes in surface structure and affected its crystallinity. The ability to adsorb CO2 and CO by AC/MgO increase up to 80% and 88%, respectively.
UR - http://www.scopus.com/inward/record.url?scp=85108588944&partnerID=8YFLogxK
U2 - 10.1088/1742-6596/1912/1/012027
DO - 10.1088/1742-6596/1912/1/012027
M3 - Conference article
AN - SCOPUS:85108588944
SN - 1742-6588
VL - 1912
JO - Journal of Physics: Conference Series
JF - Journal of Physics: Conference Series
IS - 1
M1 - 012027
T2 - 5th International Conference on Advanced Material for Better Future 2020, ICAMBF 2020
Y2 - 13 October 2020 through 14 October 2020
ER -