Co3O4nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate

Anita Pinalia; Yoki Yulizar; Heri Budi Wibowo; Dewangga Oky Bagus Apriandanu

doi:10.1063/5.0003431

Co₃O₄nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate

Anita Pinalia, Yoki Yulizar, Heri Budi Wibowo, Dewangga Oky Bagus Apriandanu

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

In this work, preparation, characterization, and catalytic activity of Co3O4 nanoparticles (NPs) are reported. Co3O4 NPs was successfully prepared using Andrographys paniculata leaves extract (APE) as a weak base source and capping agent. Characterization was conducted using Fourier transform-infrared (FT-IR) spectroscopy, x-ray diffraction (XRD), energy dispersive x-ray (EDX), and transmission electron microscopy (TEM). According to FT-IR result, there were two main absorption peaks which corresponded to Co (II)-O and Co (III)-O bond at the wave number of 664.49 and 569.01 cm-1, respectively. XRD pattern confirmed that Co3O4 particles were theoretically hexagonal with nanocrystals form. EDX analysis revealed that Cobalt and Oxygen were the main atomic content on Co3O4. The formed Co3O4 NPs has particle size of approximately 20 nm. The catalytic activity of Co3O4 NPs was tested towards thermal decomposition of ammonium perchlorate (AP) by measuring differential scanning calorimetry (DSC). The temperature decrease on thermal decomposition of AP was found to be 157 °C at temperature range of 463 and 306 °C with decreasing of activation energy from 60.43 to 36.28 kJ/mol.

Original language	English
Title of host publication	7th International Seminar on Aerospace Science and Technology, ISAST 2019
Editors	Idris Eko Putro, Frida Kurniawati, Andreas Prasetya Adi, Sayr Bahri
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735419858
DOIs	https://doi.org/10.1063/5.0003431
Publication status	Published - 21 Apr 2020
Event	7th International Seminar on Aerospace Science and Technology, ISAST 2019 - Jakarta, Indonesia Duration: 24 Sept 2019 → 25 Sept 2019

Publication series

Name	AIP Conference Proceedings
Volume	2226
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	7th International Seminar on Aerospace Science and Technology, ISAST 2019
Country/Territory	Indonesia
City	Jakarta
Period	24/09/19 → 25/09/19

Access to Document

10.1063/5.0003431

Cite this

Pinalia, A., Yulizar, Y., Wibowo, H. B., & Apriandanu, D. O. B. (2020). Co₃O₄nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate. In I. E. Putro, F. Kurniawati, A. P. Adi, & S. Bahri (Eds.), 7th International Seminar on Aerospace Science and Technology, ISAST 2019 Article 040009 (AIP Conference Proceedings; Vol. 2226). American Institute of Physics Inc.. https://doi.org/10.1063/5.0003431

Pinalia, Anita ; Yulizar, Yoki ; Wibowo, Heri Budi et al. / Co₃O₄nanoparticles : Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate. 7th International Seminar on Aerospace Science and Technology, ISAST 2019. editor / Idris Eko Putro ; Frida Kurniawati ; Andreas Prasetya Adi ; Sayr Bahri. American Institute of Physics Inc., 2020. (AIP Conference Proceedings).

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title = "Co3O4nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate",

abstract = "In this work, preparation, characterization, and catalytic activity of Co3O4 nanoparticles (NPs) are reported. Co3O4 NPs was successfully prepared using Andrographys paniculata leaves extract (APE) as a weak base source and capping agent. Characterization was conducted using Fourier transform-infrared (FT-IR) spectroscopy, x-ray diffraction (XRD), energy dispersive x-ray (EDX), and transmission electron microscopy (TEM). According to FT-IR result, there were two main absorption peaks which corresponded to Co (II)-O and Co (III)-O bond at the wave number of 664.49 and 569.01 cm-1, respectively. XRD pattern confirmed that Co3O4 particles were theoretically hexagonal with nanocrystals form. EDX analysis revealed that Cobalt and Oxygen were the main atomic content on Co3O4. The formed Co3O4 NPs has particle size of approximately 20 nm. The catalytic activity of Co3O4 NPs was tested towards thermal decomposition of ammonium perchlorate (AP) by measuring differential scanning calorimetry (DSC). The temperature decrease on thermal decomposition of AP was found to be 157 °C at temperature range of 463 and 306 °C with decreasing of activation energy from 60.43 to 36.28 kJ/mol.",

author = "Anita Pinalia and Yoki Yulizar and Wibowo, {Heri Budi} and Apriandanu, {Dewangga Oky Bagus}",

note = "Funding Information: The authors would like to thank Universitas Indonesia for funding this research through PIT-9 Grant Universitas Indonesia with contract number: NKB-0037/UN2.R3.1/HKP.05.00/2019 and Ministry of Research, Technology and Higher Education of the Republic of Indonesia through SAINTEK scholarship. Publisher Copyright: {\textcopyright} 2020 Author(s).; 7th International Seminar on Aerospace Science and Technology, ISAST 2019 ; Conference date: 24-09-2019 Through 25-09-2019",

year = "2020",

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doi = "10.1063/5.0003431",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

editor = "Putro, {Idris Eko} and Frida Kurniawati and Adi, {Andreas Prasetya} and Sayr Bahri",

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Pinalia, A, Yulizar, Y , Wibowo, HB & Apriandanu, DOB 2020, Co₃O₄nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate. in IE Putro, F Kurniawati, AP Adi & S Bahri (eds), 7th International Seminar on Aerospace Science and Technology, ISAST 2019., 040009, AIP Conference Proceedings, vol. 2226, American Institute of Physics Inc., 7th International Seminar on Aerospace Science and Technology, ISAST 2019, Jakarta, Indonesia, 24/09/19. https://doi.org/10.1063/5.0003431

Co₃O₄nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate. / Pinalia, Anita; Yulizar, Yoki ; Wibowo, Heri Budi et al.
7th International Seminar on Aerospace Science and Technology, ISAST 2019. ed. / Idris Eko Putro; Frida Kurniawati; Andreas Prasetya Adi; Sayr Bahri. American Institute of Physics Inc., 2020. 040009 (AIP Conference Proceedings; Vol. 2226).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Co3O4nanoparticles

T2 - 7th International Seminar on Aerospace Science and Technology, ISAST 2019

AU - Pinalia, Anita

AU - Yulizar, Yoki

AU - Wibowo, Heri Budi

AU - Apriandanu, Dewangga Oky Bagus

N1 - Funding Information: The authors would like to thank Universitas Indonesia for funding this research through PIT-9 Grant Universitas Indonesia with contract number: NKB-0037/UN2.R3.1/HKP.05.00/2019 and Ministry of Research, Technology and Higher Education of the Republic of Indonesia through SAINTEK scholarship. Publisher Copyright: © 2020 Author(s).

PY - 2020/4/21

Y1 - 2020/4/21

N2 - In this work, preparation, characterization, and catalytic activity of Co3O4 nanoparticles (NPs) are reported. Co3O4 NPs was successfully prepared using Andrographys paniculata leaves extract (APE) as a weak base source and capping agent. Characterization was conducted using Fourier transform-infrared (FT-IR) spectroscopy, x-ray diffraction (XRD), energy dispersive x-ray (EDX), and transmission electron microscopy (TEM). According to FT-IR result, there were two main absorption peaks which corresponded to Co (II)-O and Co (III)-O bond at the wave number of 664.49 and 569.01 cm-1, respectively. XRD pattern confirmed that Co3O4 particles were theoretically hexagonal with nanocrystals form. EDX analysis revealed that Cobalt and Oxygen were the main atomic content on Co3O4. The formed Co3O4 NPs has particle size of approximately 20 nm. The catalytic activity of Co3O4 NPs was tested towards thermal decomposition of ammonium perchlorate (AP) by measuring differential scanning calorimetry (DSC). The temperature decrease on thermal decomposition of AP was found to be 157 °C at temperature range of 463 and 306 °C with decreasing of activation energy from 60.43 to 36.28 kJ/mol.

AB - In this work, preparation, characterization, and catalytic activity of Co3O4 nanoparticles (NPs) are reported. Co3O4 NPs was successfully prepared using Andrographys paniculata leaves extract (APE) as a weak base source and capping agent. Characterization was conducted using Fourier transform-infrared (FT-IR) spectroscopy, x-ray diffraction (XRD), energy dispersive x-ray (EDX), and transmission electron microscopy (TEM). According to FT-IR result, there were two main absorption peaks which corresponded to Co (II)-O and Co (III)-O bond at the wave number of 664.49 and 569.01 cm-1, respectively. XRD pattern confirmed that Co3O4 particles were theoretically hexagonal with nanocrystals form. EDX analysis revealed that Cobalt and Oxygen were the main atomic content on Co3O4. The formed Co3O4 NPs has particle size of approximately 20 nm. The catalytic activity of Co3O4 NPs was tested towards thermal decomposition of ammonium perchlorate (AP) by measuring differential scanning calorimetry (DSC). The temperature decrease on thermal decomposition of AP was found to be 157 °C at temperature range of 463 and 306 °C with decreasing of activation energy from 60.43 to 36.28 kJ/mol.

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U2 - 10.1063/5.0003431

DO - 10.1063/5.0003431

M3 - Conference contribution

AN - SCOPUS:85113474615

T3 - AIP Conference Proceedings

BT - 7th International Seminar on Aerospace Science and Technology, ISAST 2019

A2 - Putro, Idris Eko

A2 - Kurniawati, Frida

A2 - Adi, Andreas Prasetya

A2 - Bahri, Sayr

PB - American Institute of Physics Inc.

Y2 - 24 September 2019 through 25 September 2019

ER -

Pinalia A, Yulizar Y , Wibowo HB, Apriandanu DOB. Co₃O₄nanoparticles: Facile preparation, characterization and their catalytic activity towards thermal decomposition of ammonium perchlorate. In Putro IE, Kurniawati F, Adi AP, Bahri S, editors, 7th International Seminar on Aerospace Science and Technology, ISAST 2019. American Institute of Physics Inc. 2020. 040009. (AIP Conference Proceedings). doi: 10.1063/5.0003431