Cellulose-Fe3O4 nanocomposite based on rice husk as catalyst for synthesis of methyl ester from waste cooking oil

L. Trisnawati; H. Helmiyati

doi:10.1088/1757-899X/763/1/012012

Cellulose-Fe₃O₄ nanocomposite based on rice husk as catalyst for synthesis of methyl ester from waste cooking oil

L. Trisnawati, H. Helmiyati

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

7 Citations (Scopus)

Abstract

Cellulose-Fe₃O₄ nanocomposite has been successfully synthesized by modifying Fe₃O₄ onto nanocellulose acetate surface derived cellulose from rice husk. It was supported by Fourier Tranform-Infrared (FT-IR) characterization, where there was absorption at 900 cm^-1, which was a characteristic for cellulose absorption, and at 572 cm^-1, which was the absorption of Fe-O. The morphology of cellulose-Fe₃O₄ nanocomposite by Scanning Electron Microscopy (SEM) having fibers shape were the characteristic of cellulose and Fe₃O₄ nanoparticle attached on the surface of nanocellulose and supported by SEM mapping. The characterization of Tunneling Electron Microscopy (TEM) obtained nano Fe₃O₄ on the nanocellulose surface with average size around 55 nm. The cellulose-Fe₃O₄ nanocomposites have the capability, as catalyst for the synthesis of methyl esters from waste cooking oil with the optimal conditions at 60 °C for 120 minutes with the obtained conversion is 77.56 %. The nanocomposite of based biopolymer with nanomagnetite active side is potential for catalysts from the used cooking oil to biodiesel as renewable energy and can replace limited fossil energy.

Original language	English
Article number	012012
Journal	IOP Conference Series: Materials Science and Engineering
Volume	763
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/763/1/012012
Publication status	Published - 28 Apr 2020
Event	3rd International Symposium on Current Progress in Functional Materials 2018, ISCPFM 2018 - Depok, Indonesia Duration: 8 Aug 2018 → 9 Aug 2018

Keywords

catalyst
cellulose
nanocomposite
rice husk
waste cooking oil

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1088/1757-899X/763/1/012012

Cite this

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title = "Cellulose-Fe3O4 nanocomposite based on rice husk as catalyst for synthesis of methyl ester from waste cooking oil",

abstract = "Cellulose-Fe3O4 nanocomposite has been successfully synthesized by modifying Fe3O4 onto nanocellulose acetate surface derived cellulose from rice husk. It was supported by Fourier Tranform-Infrared (FT-IR) characterization, where there was absorption at 900 cm-1, which was a characteristic for cellulose absorption, and at 572 cm-1, which was the absorption of Fe-O. The morphology of cellulose-Fe3O4 nanocomposite by Scanning Electron Microscopy (SEM) having fibers shape were the characteristic of cellulose and Fe3O4 nanoparticle attached on the surface of nanocellulose and supported by SEM mapping. The characterization of Tunneling Electron Microscopy (TEM) obtained nano Fe3O4 on the nanocellulose surface with average size around 55 nm. The cellulose-Fe3O4 nanocomposites have the capability, as catalyst for the synthesis of methyl esters from waste cooking oil with the optimal conditions at 60 °C for 120 minutes with the obtained conversion is 77.56 %. The nanocomposite of based biopolymer with nanomagnetite active side is potential for catalysts from the used cooking oil to biodiesel as renewable energy and can replace limited fossil energy.",

keywords = "catalyst, cellulose, nanocomposite, rice husk, waste cooking oil",

author = "L. Trisnawati and H. Helmiyati",

note = "Funding Information: A ck n o w le d g e me n ts The authors would like to thank Universitas Indonesia for funding this research through PITTA Grant 2018 with contract No: 2268/UN2.R3.1/HKP.05.00/2018 Re fe re n c e s [1] PodeR2016Renew.Sustain.EnergyRev.531468–85 [2] Helmiyati,AbbasG H andKurniawan S2017 IOPConf.Ser.:Mater.Sci.Eng.188012024 [3] BattegazzoreD,BocchiniS,AlongiJ,FracheAandMarinoF2014Cellulose211813–21 [4] AzadSandMirjaliliBBF2016RSC Adv696928–34 [5] MaJ,LiXandBaoY2015RSC Adv5 59745–57 [6] El-NahasAM,SalaheldinTA,ZakiT,El-MaghrabiHH,MarieAM,MorsySM andAllamN K 2017 Chem. Eng. J. 322 167–80 [7] M{\"u}llerKetal.2017 Nanomaterials7 E74 [8] ZareiS,NiadMandRaanaeiH2018J.Hazard.Mater.344258–73 [9] CaiJ,Liu S,Feng J,Kimura S,Wada M,Kuga S and Zhang L 2012 Angew.Chem.Int.Ed. Engl. 51 2076–9 [10] Helmiyati and Dini F W 2018 AIP Conf. Proc. 2023 020101 [11] Arumugam A and Ponnusami V 2017 Heliyon 3 e00486 [12] Gashaw A, Getachew T and Teshita A 2015 Journal of Forest Products and Industries (JFPI) 4 80–5 [13] Farooq M, Ramli A and Subbarao D 2013 J. Clean Prod. 59 131–40 [14] Helmiyati, Saefumillah A and Yulianti W 2014 Asian J Chem 26 7337–42 [15] Helmiyati, Fitriyani A and Meyanti F 2017 IOP Conf. Ser.: Mater. Sci. Eng. 188 012051 [16] Maleki A, Ghamari N and Kamalzare M 2014 RSC Adv. 4 9416–23 [17] Alsharifi M, Znad H, Hena S and Ang M 2017 Renew. Energy 114 1077–89 Publisher Copyright: {\textcopyright} 2020 Published under licence by IOP Publishing Ltd.; 3rd International Symposium on Current Progress in Functional Materials 2018, ISCPFM 2018 ; Conference date: 08-08-2018 Through 09-08-2018",

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T1 - Cellulose-Fe3O4 nanocomposite based on rice husk as catalyst for synthesis of methyl ester from waste cooking oil

AU - Trisnawati, L.

AU - Helmiyati, H.

N1 - Funding Information: A ck n o w le d g e me n ts The authors would like to thank Universitas Indonesia for funding this research through PITTA Grant 2018 with contract No: 2268/UN2.R3.1/HKP.05.00/2018 Re fe re n c e s [1] PodeR2016Renew.Sustain.EnergyRev.531468–85 [2] Helmiyati,AbbasG H andKurniawan S2017 IOPConf.Ser.:Mater.Sci.Eng.188012024 [3] BattegazzoreD,BocchiniS,AlongiJ,FracheAandMarinoF2014Cellulose211813–21 [4] AzadSandMirjaliliBBF2016RSC Adv696928–34 [5] MaJ,LiXandBaoY2015RSC Adv5 59745–57 [6] El-NahasAM,SalaheldinTA,ZakiT,El-MaghrabiHH,MarieAM,MorsySM andAllamN K 2017 Chem. Eng. J. 322 167–80 [7] MüllerKetal.2017 Nanomaterials7 E74 [8] ZareiS,NiadMandRaanaeiH2018J.Hazard.Mater.344258–73 [9] CaiJ,Liu S,Feng J,Kimura S,Wada M,Kuga S and Zhang L 2012 Angew.Chem.Int.Ed. Engl. 51 2076–9 [10] Helmiyati and Dini F W 2018 AIP Conf. Proc. 2023 020101 [11] Arumugam A and Ponnusami V 2017 Heliyon 3 e00486 [12] Gashaw A, Getachew T and Teshita A 2015 Journal of Forest Products and Industries (JFPI) 4 80–5 [13] Farooq M, Ramli A and Subbarao D 2013 J. Clean Prod. 59 131–40 [14] Helmiyati, Saefumillah A and Yulianti W 2014 Asian J Chem 26 7337–42 [15] Helmiyati, Fitriyani A and Meyanti F 2017 IOP Conf. Ser.: Mater. Sci. Eng. 188 012051 [16] Maleki A, Ghamari N and Kamalzare M 2014 RSC Adv. 4 9416–23 [17] Alsharifi M, Znad H, Hena S and Ang M 2017 Renew. Energy 114 1077–89 Publisher Copyright: © 2020 Published under licence by IOP Publishing Ltd.

PY - 2020/4/28

Y1 - 2020/4/28

N2 - Cellulose-Fe3O4 nanocomposite has been successfully synthesized by modifying Fe3O4 onto nanocellulose acetate surface derived cellulose from rice husk. It was supported by Fourier Tranform-Infrared (FT-IR) characterization, where there was absorption at 900 cm-1, which was a characteristic for cellulose absorption, and at 572 cm-1, which was the absorption of Fe-O. The morphology of cellulose-Fe3O4 nanocomposite by Scanning Electron Microscopy (SEM) having fibers shape were the characteristic of cellulose and Fe3O4 nanoparticle attached on the surface of nanocellulose and supported by SEM mapping. The characterization of Tunneling Electron Microscopy (TEM) obtained nano Fe3O4 on the nanocellulose surface with average size around 55 nm. The cellulose-Fe3O4 nanocomposites have the capability, as catalyst for the synthesis of methyl esters from waste cooking oil with the optimal conditions at 60 °C for 120 minutes with the obtained conversion is 77.56 %. The nanocomposite of based biopolymer with nanomagnetite active side is potential for catalysts from the used cooking oil to biodiesel as renewable energy and can replace limited fossil energy.

AB - Cellulose-Fe3O4 nanocomposite has been successfully synthesized by modifying Fe3O4 onto nanocellulose acetate surface derived cellulose from rice husk. It was supported by Fourier Tranform-Infrared (FT-IR) characterization, where there was absorption at 900 cm-1, which was a characteristic for cellulose absorption, and at 572 cm-1, which was the absorption of Fe-O. The morphology of cellulose-Fe3O4 nanocomposite by Scanning Electron Microscopy (SEM) having fibers shape were the characteristic of cellulose and Fe3O4 nanoparticle attached on the surface of nanocellulose and supported by SEM mapping. The characterization of Tunneling Electron Microscopy (TEM) obtained nano Fe3O4 on the nanocellulose surface with average size around 55 nm. The cellulose-Fe3O4 nanocomposites have the capability, as catalyst for the synthesis of methyl esters from waste cooking oil with the optimal conditions at 60 °C for 120 minutes with the obtained conversion is 77.56 %. The nanocomposite of based biopolymer with nanomagnetite active side is potential for catalysts from the used cooking oil to biodiesel as renewable energy and can replace limited fossil energy.

KW - catalyst

KW - cellulose

KW - nanocomposite

KW - rice husk

KW - waste cooking oil

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DO - 10.1088/1757-899X/763/1/012012

M3 - Conference article

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