TY - JOUR
T1 - Catalytic Conversion of Beef Tallow to Biofuels using MgO Nanoparticles Green Synthesized by Zingiber officinale Roscoe Rhizome Extract
AU - Riyadhi, Adi
AU - Yulizar, Yoki
AU - Susanto, Bambang Heru
N1 - Funding Information:
The Indonesia Endowment Fund for Education funded this research, Ministry of Finance, Republik Indonesia (LPDP Kementerian Keuangan RI) for the Scholarships and Research Grants (No. S-168/LPDP.3/2017).
Publisher Copyright:
© 2022,International Journal of Technology. All Rights Reserved.
PY - 2022
Y1 - 2022
N2 - MgO nanoparticles (MgONPs) have been successfully synthesized using ZOE (Zingiber officinale Roscoe extract in water) and applied for catalytic conversion of beef tallow to biogasoline, kerosene, and diesel. ZOE was used due to containing the alkaloid as a weak base source to hydrolyze Mg(NO3)2 precursor and form the MgONPs. The synthesized MgONPs were characterized using UV-Vis spectrophotometer, X-ray diffraction (XRD), particle size analyzer (PSA), Brunauer−Emmett−Teller (BET) surface areas. UV–Vis diffuse reflectance spectrophotometry (DRS), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX), and transmission electron microscopy (TEM). The catalyst activity was performed to convert beef tallow to biofuel in the stainless-steel reactors at 300 ᵒC for 60 min. The conversion results of beef tallow were analyzed using gas chromatography-mass spectrometry (GC-MS). The beef tallow conversion shows that all fatty acids derived from beef tallow are converted to gases and liquids fractions. The conversion using a catalyst to feed weight ratio of 4 wt. % produced the liquid fractions containing the dominant alkanes (62.85%) and cyclic compounds (18.77%). Pentadecane and Heptadecane are liquid products' main compounds, indicating a decarboxylation reaction.
AB - MgO nanoparticles (MgONPs) have been successfully synthesized using ZOE (Zingiber officinale Roscoe extract in water) and applied for catalytic conversion of beef tallow to biogasoline, kerosene, and diesel. ZOE was used due to containing the alkaloid as a weak base source to hydrolyze Mg(NO3)2 precursor and form the MgONPs. The synthesized MgONPs were characterized using UV-Vis spectrophotometer, X-ray diffraction (XRD), particle size analyzer (PSA), Brunauer−Emmett−Teller (BET) surface areas. UV–Vis diffuse reflectance spectrophotometry (DRS), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX), and transmission electron microscopy (TEM). The catalyst activity was performed to convert beef tallow to biofuel in the stainless-steel reactors at 300 ᵒC for 60 min. The conversion results of beef tallow were analyzed using gas chromatography-mass spectrometry (GC-MS). The beef tallow conversion shows that all fatty acids derived from beef tallow are converted to gases and liquids fractions. The conversion using a catalyst to feed weight ratio of 4 wt. % produced the liquid fractions containing the dominant alkanes (62.85%) and cyclic compounds (18.77%). Pentadecane and Heptadecane are liquid products' main compounds, indicating a decarboxylation reaction.
KW - Beef tallow
KW - Decarboxylation
KW - Mgo nanoparticles
KW - Zingiber officinale roscoe
UR - http://www.scopus.com/inward/record.url?scp=85141241519&partnerID=8YFLogxK
U2 - 10.14716/ijtech.v13i4.4821
DO - 10.14716/ijtech.v13i4.4821
M3 - Article
AN - SCOPUS:85141241519
SN - 2086-9614
VL - 13
SP - 900
EP - 911
JO - International Journal of Technology
JF - International Journal of Technology
IS - 4
ER -