Carbon modification on the surface of Li4Al0.03Ti4.97O12using pyrolysis process for anode of lithium ion battery

Slamet Priyono; Muhammad Dzulqornain; Ilham Nur Dimas Yahya; Muchtazar Yusril Izha; Abdulloh Rifai; Titik Lestariningsih; Wahyu Bambang Widayatno; Akhmad Herman Yuwono

doi:10.1063/5.0107413

Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery

Slamet Priyono, Muhammad Dzulqornain, Ilham Nur Dimas Yahya, Muchtazar Yusril Izha, Abdulloh Rifai, Titik Lestariningsih, Wahyu Bambang Widayatno, Akhmad Herman Yuwono

Department of Metallurgical and Material Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The surface of Li4Al0.03Ti4.97O12 was successfully modified using carbon from sugar. Li4Al0.03Ti4.97O12 samples were obtained via sol-gel route through the sintering of 850°C for 4 hours at room atmosphere. While the modifying process using sugar as carbon sources was conducted by pyrolysis process at 600°C for 2 hours under N2 atmosphere. Removing carbon process from Li4Al0.03Ti4.97O12 was done by sintering again at 600°C for 2 hours under air atmosphere. There are three samples, pure, carbon-modified, and carbon-removed of Li4Al0.03Ti4.97O12, prepared in this report. Characterizations were conducted using XRD, FESEM, EIS, CV and CD to know the phases, morphology, conductivity, electrochemistry, and specific capacity, respectively. XRD patterns confirmed the spinel structure of Li4Al0.03Ti4.97O12 and rutile as impurity phase. There are not any Al phases indicated that Al ion enters the spinel. Carbon-modified significantly changed the morphology of sample. However, carbon from sugar decrease the ionic diffusion, specific capacity, and power density. The highest specific capacity achieved by pure Li4Al0.03Ti4.97O12 can reach of 150 mAh/g and it can be discharge until 10 C.

Original language	English
Title of host publication	6th International Symposium on Frontier of Applied Physics, ISFAP 2021
Editors	Mohammad Hamzah Fauzi, Gagus Ketut Sunnardiarto, Mohammad Hasib, Sasfan Arman Wella, Apriadi Salim Adam, M. Jauhar Kholili, Wahyu Dita Saputri, Seramika Ariwahjoedi, Syuhada, Gerald Ensang Timuda, Dwi Hanto, Yuliati Herbani, Witha Berlian Kesuma Putri, Iyon Titok Sugiarto, Deni Shidqi Khaerundini, Ahmad Ridwan T. Nugraha, Edi Suprayoga, Muhandis Shiddiq, Andri Hardiansyah, Salim Mustofa
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735442641
DOIs	https://doi.org/10.1063/5.0107413
Publication status	Published - 14 Nov 2022
Event	6th International Symposium on Frontier of Applied Physics, ISFAP 2021 - South Tangerang, Indonesia Duration: 6 Oct 2021 → 7 Oct 2021

Publication series

Name	AIP Conference Proceedings
Volume	2652
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	6th International Symposium on Frontier of Applied Physics, ISFAP 2021
Country/Territory	Indonesia
City	South Tangerang
Period	6/10/21 → 7/10/21

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1063/5.0107413

Cite this

Priyono, S., Dzulqornain, M., Yahya, I. N. D., Izha, M. Y., Rifai, A., Lestariningsih, T., Widayatno, W. B., & Yuwono, A. H. (2022). Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery. In M. H. Fauzi, G. K. Sunnardiarto, M. Hasib, S. A. Wella, A. S. Adam, M. J. Kholili, W. D. Saputri, S. Ariwahjoedi, Syuhada, G. E. Timuda, D. Hanto, Y. Herbani, W. B. K. Putri, I. T. Sugiarto, D. S. Khaerundini, A. R. T. Nugraha, E. Suprayoga, M. Shiddiq, A. Hardiansyah, & S. Mustofa (Eds.), 6th International Symposium on Frontier of Applied Physics, ISFAP 2021 Article 040008 (AIP Conference Proceedings; Vol. 2652). American Institute of Physics Inc.. https://doi.org/10.1063/5.0107413

Priyono, Slamet ; Dzulqornain, Muhammad ; Yahya, Ilham Nur Dimas et al. / Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery. 6th International Symposium on Frontier of Applied Physics, ISFAP 2021. editor / Mohammad Hamzah Fauzi ; Gagus Ketut Sunnardiarto ; Mohammad Hasib ; Sasfan Arman Wella ; Apriadi Salim Adam ; M. Jauhar Kholili ; Wahyu Dita Saputri ; Seramika Ariwahjoedi ; Syuhada ; Gerald Ensang Timuda ; Dwi Hanto ; Yuliati Herbani ; Witha Berlian Kesuma Putri ; Iyon Titok Sugiarto ; Deni Shidqi Khaerundini ; Ahmad Ridwan T. Nugraha ; Edi Suprayoga ; Muhandis Shiddiq ; Andri Hardiansyah ; Salim Mustofa. American Institute of Physics Inc., 2022. (AIP Conference Proceedings).

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title = "Carbon modification on the surface of Li4Al0.03Ti4.97O12using pyrolysis process for anode of lithium ion battery",

abstract = "The surface of Li4Al0.03Ti4.97O12 was successfully modified using carbon from sugar. Li4Al0.03Ti4.97O12 samples were obtained via sol-gel route through the sintering of 850°C for 4 hours at room atmosphere. While the modifying process using sugar as carbon sources was conducted by pyrolysis process at 600°C for 2 hours under N2 atmosphere. Removing carbon process from Li4Al0.03Ti4.97O12 was done by sintering again at 600°C for 2 hours under air atmosphere. There are three samples, pure, carbon-modified, and carbon-removed of Li4Al0.03Ti4.97O12, prepared in this report. Characterizations were conducted using XRD, FESEM, EIS, CV and CD to know the phases, morphology, conductivity, electrochemistry, and specific capacity, respectively. XRD patterns confirmed the spinel structure of Li4Al0.03Ti4.97O12 and rutile as impurity phase. There are not any Al phases indicated that Al ion enters the spinel. Carbon-modified significantly changed the morphology of sample. However, carbon from sugar decrease the ionic diffusion, specific capacity, and power density. The highest specific capacity achieved by pure Li4Al0.03Ti4.97O12 can reach of 150 mAh/g and it can be discharge until 10 C.",

author = "Slamet Priyono and Muhammad Dzulqornain and Yahya, {Ilham Nur Dimas} and Izha, {Muchtazar Yusril} and Abdulloh Rifai and Titik Lestariningsih and Widayatno, {Wahyu Bambang} and Yuwono, {Akhmad Herman}",

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year = "2022",

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doi = "10.1063/5.0107413",

language = "English",

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editor = "Fauzi, {Mohammad Hamzah} and Sunnardiarto, {Gagus Ketut} and Mohammad Hasib and Wella, {Sasfan Arman} and Adam, {Apriadi Salim} and Kholili, {M. Jauhar} and Saputri, {Wahyu Dita} and Seramika Ariwahjoedi and Syuhada and Timuda, {Gerald Ensang} and Dwi Hanto and Yuliati Herbani and Putri, {Witha Berlian Kesuma} and Sugiarto, {Iyon Titok} and Khaerundini, {Deni Shidqi} and Nugraha, {Ahmad Ridwan T.} and Edi Suprayoga and Muhandis Shiddiq and Andri Hardiansyah and Salim Mustofa",

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Priyono, S, Dzulqornain, M, Yahya, IND, Izha, MY, Rifai, A, Lestariningsih, T, Widayatno, WB & Yuwono, AH 2022, Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery. in MH Fauzi, GK Sunnardiarto, M Hasib, SA Wella, AS Adam, MJ Kholili, WD Saputri, S Ariwahjoedi, Syuhada, GE Timuda, D Hanto, Y Herbani, WBK Putri, IT Sugiarto, DS Khaerundini, ART Nugraha, E Suprayoga, M Shiddiq, A Hardiansyah & S Mustofa (eds), 6th International Symposium on Frontier of Applied Physics, ISFAP 2021., 040008, AIP Conference Proceedings, vol. 2652, American Institute of Physics Inc., 6th International Symposium on Frontier of Applied Physics, ISFAP 2021, South Tangerang, Indonesia, 6/10/21. https://doi.org/10.1063/5.0107413

Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery. / Priyono, Slamet; Dzulqornain, Muhammad; Yahya, Ilham Nur Dimas et al.
6th International Symposium on Frontier of Applied Physics, ISFAP 2021. ed. / Mohammad Hamzah Fauzi; Gagus Ketut Sunnardiarto; Mohammad Hasib; Sasfan Arman Wella; Apriadi Salim Adam; M. Jauhar Kholili; Wahyu Dita Saputri; Seramika Ariwahjoedi; Syuhada; Gerald Ensang Timuda; Dwi Hanto; Yuliati Herbani; Witha Berlian Kesuma Putri; Iyon Titok Sugiarto; Deni Shidqi Khaerundini; Ahmad Ridwan T. Nugraha; Edi Suprayoga; Muhandis Shiddiq; Andri Hardiansyah; Salim Mustofa. American Institute of Physics Inc., 2022. 040008 (AIP Conference Proceedings; Vol. 2652).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Carbon modification on the surface of Li4Al0.03Ti4.97O12using pyrolysis process for anode of lithium ion battery

AU - Priyono, Slamet

AU - Dzulqornain, Muhammad

AU - Yahya, Ilham Nur Dimas

AU - Izha, Muchtazar Yusril

AU - Rifai, Abdulloh

AU - Lestariningsih, Titik

AU - Widayatno, Wahyu Bambang

AU - Yuwono, Akhmad Herman

PY - 2022/11/14

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N2 - The surface of Li4Al0.03Ti4.97O12 was successfully modified using carbon from sugar. Li4Al0.03Ti4.97O12 samples were obtained via sol-gel route through the sintering of 850°C for 4 hours at room atmosphere. While the modifying process using sugar as carbon sources was conducted by pyrolysis process at 600°C for 2 hours under N2 atmosphere. Removing carbon process from Li4Al0.03Ti4.97O12 was done by sintering again at 600°C for 2 hours under air atmosphere. There are three samples, pure, carbon-modified, and carbon-removed of Li4Al0.03Ti4.97O12, prepared in this report. Characterizations were conducted using XRD, FESEM, EIS, CV and CD to know the phases, morphology, conductivity, electrochemistry, and specific capacity, respectively. XRD patterns confirmed the spinel structure of Li4Al0.03Ti4.97O12 and rutile as impurity phase. There are not any Al phases indicated that Al ion enters the spinel. Carbon-modified significantly changed the morphology of sample. However, carbon from sugar decrease the ionic diffusion, specific capacity, and power density. The highest specific capacity achieved by pure Li4Al0.03Ti4.97O12 can reach of 150 mAh/g and it can be discharge until 10 C.

AB - The surface of Li4Al0.03Ti4.97O12 was successfully modified using carbon from sugar. Li4Al0.03Ti4.97O12 samples were obtained via sol-gel route through the sintering of 850°C for 4 hours at room atmosphere. While the modifying process using sugar as carbon sources was conducted by pyrolysis process at 600°C for 2 hours under N2 atmosphere. Removing carbon process from Li4Al0.03Ti4.97O12 was done by sintering again at 600°C for 2 hours under air atmosphere. There are three samples, pure, carbon-modified, and carbon-removed of Li4Al0.03Ti4.97O12, prepared in this report. Characterizations were conducted using XRD, FESEM, EIS, CV and CD to know the phases, morphology, conductivity, electrochemistry, and specific capacity, respectively. XRD patterns confirmed the spinel structure of Li4Al0.03Ti4.97O12 and rutile as impurity phase. There are not any Al phases indicated that Al ion enters the spinel. Carbon-modified significantly changed the morphology of sample. However, carbon from sugar decrease the ionic diffusion, specific capacity, and power density. The highest specific capacity achieved by pure Li4Al0.03Ti4.97O12 can reach of 150 mAh/g and it can be discharge until 10 C.

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BT - 6th International Symposium on Frontier of Applied Physics, ISFAP 2021

A2 - Fauzi, Mohammad Hamzah

A2 - Sunnardiarto, Gagus Ketut

A2 - Hasib, Mohammad

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Priyono S, Dzulqornain M, Yahya IND, Izha MY, Rifai A, Lestariningsih T et al. Carbon modification on the surface of Li₄Al_0.03Ti_4.97O₁₂using pyrolysis process for anode of lithium ion battery. In Fauzi MH, Sunnardiarto GK, Hasib M, Wella SA, Adam AS, Kholili MJ, Saputri WD, Ariwahjoedi S, Syuhada, Timuda GE, Hanto D, Herbani Y, Putri WBK, Sugiarto IT, Khaerundini DS, Nugraha ART, Suprayoga E, Shiddiq M, Hardiansyah A, Mustofa S, editors, 6th International Symposium on Frontier of Applied Physics, ISFAP 2021. American Institute of Physics Inc. 2022. 040008. (AIP Conference Proceedings). doi: 10.1063/5.0107413