TY - GEN
T1 - Blending effect in Li2O-P2O5-MMT solid electrolyte and its contribution to conductivity value
AU - Jodi, Heri
AU - Yulianti, Evi
AU - Sudjatno, Agus
AU - Syahrial, Anne Zulfia
AU - Kartini, Evvy
N1 - Funding Information:
We would like to thank our colleagues at The Center for Science and Technology of Advanced Materials in BATAN as well as those from the Department of Metallurgy and Materials Engineering at Universitas Indonesia. This work was funded by the Indonesian Ministry of Research, Technology, and Higher Education of the Republic of Indonesia under the Doctoral Scholarship Fund.
Publisher Copyright:
© 2021 Author(s).
PY - 2021/11/11
Y1 - 2021/11/11
N2 - Preparing solid electrolytes through solid reaction processes in certain compositions and temperatures leaves the possibility of forming impurity phases in the reaction products, which affect their conductivity. However, the type and quantity of the impurity phase cannot be predicted from the beginning of the reaction. In this study, the Montmorillonite was mixed as a measured parameter with the precursors of the 1.5Li2O-P2O5 compound, to determine its effect on the quality of the reaction product and its conductivity. The material synthesis was carried out by the solid-state reaction method through the melt quenching technique. The characterization was carried out by using Electrochemical Impedance Spectrometry (EIS) and X-Ray Diffractometer (XRD). The value of conductivity is dominated by the conductivity of the dominant phase Li4P2O7. The addition of MMT affected the lattice parameter of the dominant phase, increased the conductivity, and reached a maximum at the addition of 25 wt%. The minor phases have a filler effect in the compound, affected the conductivity, in the form of a matrix to filler ratio of a composite.
AB - Preparing solid electrolytes through solid reaction processes in certain compositions and temperatures leaves the possibility of forming impurity phases in the reaction products, which affect their conductivity. However, the type and quantity of the impurity phase cannot be predicted from the beginning of the reaction. In this study, the Montmorillonite was mixed as a measured parameter with the precursors of the 1.5Li2O-P2O5 compound, to determine its effect on the quality of the reaction product and its conductivity. The material synthesis was carried out by the solid-state reaction method through the melt quenching technique. The characterization was carried out by using Electrochemical Impedance Spectrometry (EIS) and X-Ray Diffractometer (XRD). The value of conductivity is dominated by the conductivity of the dominant phase Li4P2O7. The addition of MMT affected the lattice parameter of the dominant phase, increased the conductivity, and reached a maximum at the addition of 25 wt%. The minor phases have a filler effect in the compound, affected the conductivity, in the form of a matrix to filler ratio of a composite.
UR - http://www.scopus.com/inward/record.url?scp=85119345541&partnerID=8YFLogxK
U2 - 10.1063/5.0066611
DO - 10.1063/5.0066611
M3 - Conference contribution
AN - SCOPUS:85119345541
T3 - AIP Conference Proceedings
BT - Proceedings of the International Conference on Nuclear Science, Technology, and Application 2020, ICONSTA 2020
A2 - Rifal, Muhammad
A2 - Mulyani, Emy
A2 - Mujamilah, null
A2 - Sugono, Irawan
A2 - Santoso, Muhayatun
A2 - Taufik, null
PB - American Institute of Physics Inc.
T2 - International Conference on Nuclear Science, Technology, and Application 2020, ICONSTA 2020
Y2 - 23 November 2020 through 24 November 2020
ER -