TY - JOUR
T1 - Biological Metal-Organic Frameworks (Bio-MOFs) for CO2Capture
AU - Zulys, Agustino
AU - Yulia, Fayza
AU - Muhadzib, Naufal
AU - Nasruddin,
N1 - Funding Information:
The authors gratefully acknowledge funding from the Ministry of Research, Technology, and Higher Education, Republic of Indonesia through PMDSU Grant NKB-445/UN2.RST/HKP.05.00/2020, the Osaka Gas Foundation and Publikasi Terindeks Internasional Q2 (PUTI Q2) through Grant NKB-1700/UN2.RST/HKP.05.00/2020 from DRPM Universitas Indonesia.
Publisher Copyright:
© 2020 American Chemical Society.
Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/1/13
Y1 - 2021/1/13
N2 - Industrialization and economic development have accelerated energy consumption and the release of CO2 to the atmosphere. The continual increase in CO2 levels is contributing to climate change; therefore, mitigating CO2 emissions warrants intensive research. Metal-organic frameworks (MOFs) have demonstrated potential as adsorbents for CO2 capture, but their cost makes them impractical for industrial applications. Inexpensive biomolecules, including amino acids, proteins, peptides, and porphyrins, can be used as ligands to manufacture biological MOFs (bio-MOFs) with diverse structures that can be tailored for CO2 adsorption. In this study, we discuss the application of bio-MOFs for CO2 capture. We review the principles of CO2 capture, bio-MOF CO2 adsorption chemistry, and industrial system requirements. We also review experimental and theoretical studies on bio-MOF structural parameters that affect CO2 adsorption efficiency, heat of adsorption, and selectivity. Next, we discuss the technical and economic challenges of applying bio-MOFs for CO2 capture and provide recommendations for their industrial-scale use.
AB - Industrialization and economic development have accelerated energy consumption and the release of CO2 to the atmosphere. The continual increase in CO2 levels is contributing to climate change; therefore, mitigating CO2 emissions warrants intensive research. Metal-organic frameworks (MOFs) have demonstrated potential as adsorbents for CO2 capture, but their cost makes them impractical for industrial applications. Inexpensive biomolecules, including amino acids, proteins, peptides, and porphyrins, can be used as ligands to manufacture biological MOFs (bio-MOFs) with diverse structures that can be tailored for CO2 adsorption. In this study, we discuss the application of bio-MOFs for CO2 capture. We review the principles of CO2 capture, bio-MOF CO2 adsorption chemistry, and industrial system requirements. We also review experimental and theoretical studies on bio-MOF structural parameters that affect CO2 adsorption efficiency, heat of adsorption, and selectivity. Next, we discuss the technical and economic challenges of applying bio-MOFs for CO2 capture and provide recommendations for their industrial-scale use.
UR - http://www.scopus.com/inward/record.url?scp=85100212035&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.0c04522
DO - 10.1021/acs.iecr.0c04522
M3 - Article
AN - SCOPUS:85100212035
SN - 0888-5885
VL - 60
SP - 37
EP - 51
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
IS - 1
ER -