Bentonite modification with pillarization method using metal stannum

Robert R. Widjaya, Ariadne Lakshmidevi, Nino Rinaldi

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Citations (Scopus)

Abstract

Clay minerals have received considerable attention in the last years because of their environmental compatibility, low cost, high selectivity, and operational simplicity. Although clays are very useful for many application in the field of catalysis, they have main disadvantage: their lack of pore volume and spesific surface area. Porosity and stability of these materials are improved by pillaring the clay layers with SnCl4, which leads to materials known as pillared clays (PILC). This research aims were to characterize the Bentonite and Sn-Bentonite as catalysts for cracking and oligomerization. The Sn-Bentonite was prepared by pillarization method with a variation in metal ratio of 5 mmol dan 10 mmol.gr-1 of bentonit. The catalyst characterized by X-ray Diffraction, X-ray Fluorescence, Fourier Transform Infra Red, Brunauer Emmett Teller, Thermogravimetric Analysis. The results showed that the Sn-Bentonite catalyst had large basal spacing and good porous structure, and the specific surface areas increased. XRF detected the Sn in the Bentonite and TGA results showed the ability Sn-Bentonite in receiving heat. FTIR test showed two type of acidity, broansted and lewis acid. The characterized results indicated that Sn-Bentonite with metal ratio 5 mmol.gr-1 better than Sn-Bentonite with metal ratio 10 mmol.gr-1, in which there was a significant increase the basal spacings, specific surface area, and pore volume. The TGA results for Sn-Bentonite appeared to be more thermally stable than Bentonite.

Original languageEnglish
Title of host publicationProceedings of the 3rd International Symposium on Applied Chemistry 2017
EditorsSilvester Tursiloadi, Nino Rinaldi
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735415942
DOIs
Publication statusPublished - 27 Nov 2017
Event3rd International Symposium on Applied Chemistry 2017, ISAC 2017 - Jakarta, Indonesia
Duration: 23 Oct 201724 Oct 2017

Publication series

NameAIP Conference Proceedings
Volume1904
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference3rd International Symposium on Applied Chemistry 2017, ISAC 2017
CountryIndonesia
CityJakarta
Period23/10/1724/10/17

Fingerprint Dive into the research topics of 'Bentonite modification with pillarization method using metal stannum'. Together they form a unique fingerprint.

Cite this