A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/ hydrosilylation catalysis

Marcus Rastätter; Agustino Zulys; Peter W. Roesky

doi:10.1039/b514242c

A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/ hydrosilylation catalysis

Marcus Rastätter, Agustino Zulys, Peter W. Roesky

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

[La{N(SiHMe₂)₂}₂{CH(PPh ₂NSiMe₃)₂}], which was obtained via an amine elimination starting from [CH₂(PPh₂NSiMe₃) ₂] and [La{N(SiHMe₂)₂}₃(THF) ₂], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction.

Original language	English
Pages (from-to)	874-876
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b514242c
Publication status	Published - 2006

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abstract = "[La{N(SiHMe2)2}2{CH(PPh 2NSiMe3)2}], which was obtained via an amine elimination starting from [CH2(PPh2NSiMe3) 2] and [La{N(SiHMe2)2}3(THF) 2], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction.",

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journal = "Chemical Communications",

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AU - Rastätter, Marcus

AU - Zulys, Agustino

AU - Roesky, Peter W.

PY - 2006

Y1 - 2006

N2 - [La{N(SiHMe2)2}2{CH(PPh 2NSiMe3)2}], which was obtained via an amine elimination starting from [CH2(PPh2NSiMe3) 2] and [La{N(SiHMe2)2}3(THF) 2], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction.

AB - [La{N(SiHMe2)2}2{CH(PPh 2NSiMe3)2}], which was obtained via an amine elimination starting from [CH2(PPh2NSiMe3) 2] and [La{N(SiHMe2)2}3(THF) 2], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction.

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DO - 10.1039/b514242c

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AN - SCOPUS:32844471161

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JF - Chemical Communications

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A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/ hydrosilylation catalysis

Abstract

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